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Easy and high yield P2P from propenylbenzene using Bi-triflate

Started by PEYOTE, November 09, 2001, 01:56:00 PM

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PEYOTE

"A facile and efficient method for the rearrangment of arylsubstituted epoxides to aldehydes and ketones using Bi-triflate.

Tetrahedron Lett. 42:8129(2001)

Whizard

Can you post this reference?

I dunno, but I been told ... You never slow down, you never grow old!


madprosr

can someone please post the bismuth triflate synthesis referenced in that pdf?
this could work like magic for asarone epoxide/glycol acetate?

madprosr


Bismuth(III) trifluoromethanesulfonate (Bi(OTf)31) can be easily prepared from the reaction of protiodemetallation of triphenylbismuth by a stoichiometric amount of trifluoromethanesulfonic acid. The intermediates Ph3-n Bi(OTf)n[n=2(2),1(3)] have been isolated. This process represents an improvement of the previously reported methods.

2 more things i don't have access to...