Actually i just worry if it was going to somewhat like emotional argumentation, and i tried to did something to redirecting to the right state , but from what you said (glad hear that) i no need to worry, sorry and thank you
I don't mind about positive argumentation and being wrong, feel free to prove me wrong.
Sure i'll gladly post it here soon i after find sulfite reference, i read it months ago so take time to find it. For R-X --> R-H low valence metal procedures i just read it days ago so i can find it easily;
Na, THF, t-BuOH (alkyl , vinilic, aryl)
ref;
OrgSyn 48 68 (1968)
JACS 108 1265 (1986), 114 5018 (1992)
JOC 53 5186 (1988), 59 661 (1994)
Mg, i-PrOH (alkyl, vinilic, aryl)
Proc Chem Soc 219 (1963)
Mg, TiCl3, THF (alkyl, aryl)
CC 781 (1985)
Zn, HOAc (alkyl, vinilic, aryl)
Org Syn Coll Vol 2 320 (1943)
JACS 91 1767 (1969)
TL 28 3225 (1987)
CrSO4, DMF, H2O (1*, 2* alkyl; allylic, benzylic)
JACS 85 2768 (1963)
I have no idea yet about the route Chloramphenicol-->amphetamine derivatives, i should do some experiments to get it.
I don't mind about positive argumentation and being wrong, feel free to prove me wrong.
Sure i'll gladly post it here soon i after find sulfite reference, i read it months ago so take time to find it. For R-X --> R-H low valence metal procedures i just read it days ago so i can find it easily;
Na, THF, t-BuOH (alkyl , vinilic, aryl)
ref;
OrgSyn 48 68 (1968)
JACS 108 1265 (1986), 114 5018 (1992)
JOC 53 5186 (1988), 59 661 (1994)
Mg, i-PrOH (alkyl, vinilic, aryl)
Proc Chem Soc 219 (1963)
Mg, TiCl3, THF (alkyl, aryl)
CC 781 (1985)
Zn, HOAc (alkyl, vinilic, aryl)
Org Syn Coll Vol 2 320 (1943)
JACS 91 1767 (1969)
TL 28 3225 (1987)
CrSO4, DMF, H2O (1*, 2* alkyl; allylic, benzylic)
JACS 85 2768 (1963)
Quote
I wonder if there are any antibiotics analogues of C. without nitro group..If you don't find it yet, there are 4 antibiotics in Amphenicol class; Chloramphenicol and Azidamphenicol for human, Thiamphenicol and Florphenicol for veterinary. I think you will be more interent to Florphenicol, sometimes it's written Florfenicol, tradename nuflor and aquaflor, no nitro arene and even no primary alcohol
I have no idea yet about the route Chloramphenicol-->amphetamine derivatives, i should do some experiments to get it.