Here's the paper (attached) if anyone is interested in it.
Methyl Man
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Enkidu
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US2871098A Production of hydrogen chloride and sulfuric acid [chlorosulfonic acid]
Enkidu
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Scanned by yours truly
Dorothy Huang Hains
STUDIES ON ELEMICIN SYNTHESES
Thesis, pub by McNeese State University in 1976
[gallic acid]
Dorothy Huang Hains
STUDIES ON ELEMICIN SYNTHESES
Thesis, pub by McNeese State University in 1976
[gallic acid]
Enkidu
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E. J. Corey and C. U. Kim
"A method for the oxidation of sec,tert-1,2-diols to ?-hydroxy ketones without carbon-carbon cleavage"
Tetrahedron Letters Volume 15, Issue 3, 1974, Pages 287-290 doi:10.1016/S0040-4039(01)82195-X
"A method for the oxidation of sec,tert-1,2-diols to ?-hydroxy ketones without carbon-carbon cleavage"
Tetrahedron Letters Volume 15, Issue 3, 1974, Pages 287-290 doi:10.1016/S0040-4039(01)82195-X
akcom
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Simple Iron Catalyst for Terminal Alkene Epoxidation
Geraud Dubois, Andrew Murphy, and T. Daniel P. Stack*
Organic Letters, 2003, Vol 5, No. 14 Page 2469-2472
pubs.acs.org/doi/abs/10.1021/ol0347085
Geraud Dubois, Andrew Murphy, and T. Daniel P. Stack*
Organic Letters, 2003, Vol 5, No. 14 Page 2469-2472
pubs.acs.org/doi/abs/10.1021/ol0347085
Quote
A mu-oxo-iron(III) dimer, [((phen)2(H2O)FeIII)2(?-O)](ClO4)4, is an efficient epoxidation catalyst for a wide range of alkenes, including terminal alkenes, using peracetic acid as the oxidant. Low catalyst loadings, in situ catalyst preparation from common reagents, fast reaction times (<5 min at 0 °C), and enhanced reaction performance at high substrate concentrations combine to create a temporally and synthetically efficient procedure for alkene epoxidation.100% conversion from both cis & trans beta methyl styrene (96% isolated yields). Epoxidation with performic/peracetic acid usually leads to relatively high yields of the glycol ester, but this cuts the reaction time down by an order of magnitude.
Enkidu
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^ They claim a process involving bromine, but never give an example..
lugh
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Quote
SO, because i not found any reference exchange thread, im starting one.
A new member doesn't have access to the forum in which that thread is in until they have the required number of posts The article you requested is published in a rather obscure journal that's not easily available online but the text of it is in the attached archive On the other hand the article that's attached:
Kinetics of Oxidative Decarboxylation of 3,4-Methylenedioxymandelic Acid to Piperonal with Dilute Nitric Acid
Hongjuan Xi†‡, Zhixian Gao*† and Jianguo Wang†
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, People’s Republic of China, and Graduate University of the Chinese Academy of Sciences, Beijing 100039, People’s Republic of China
Ind. Eng. Chem. Res., 2009, 48 (23), pp 10425–10430
DOI: 10.1021/ie900961r
is more easily found and discusses the subject you're interested in Your request made via pm isn't possible Once you participate in this forum for a little while you'll have access to the references section
RoidRage
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It's not convenient at all but I found it elegant and though some members might be interested into reading it
Facile and Enantiospecific Syntheses of (6S,7R)-6-Chloro-7-benzyloxy-, (7S)-Halo-, and (7S)-Hydroxy-cocaine and Natural (?)-Cocaine from d-(?)-Ribose
Org. Lett., 2011, 13 (11), pp 2916–2919
Tony K. M. Shing* and King H. So
DOI: 10.1021/ol2009686
Facile and Enantiospecific Syntheses of (6S,7R)-6-Chloro-7-benzyloxy-, (7S)-Halo-, and (7S)-Hydroxy-cocaine and Natural (?)-Cocaine from d-(?)-Ribose
Org. Lett., 2011, 13 (11), pp 2916–2919
Tony K. M. Shing* and King H. So
DOI: 10.1021/ol2009686
Assyl Fartrate
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Basic opioid pharmacology...
Assyl Fartrate
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Some fentanyl stuff...
Assyl Fartrate
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Two ohmefentanyl articles followed by a study done with heroin users rating the pleasurability of morphine, heroin, oxycodone, fentanyl, etc...
Assyl Fartrate
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These two articles are among the most exciting Assyl has ever read... oxycodone analogs easily made from oxycodone itself in a single step, which have potencies ranging from 100-24,000x morphine, with far less dangerous respiratory depression, less unpleasant ones such as constipation, physical coordination problems, sedation, and physical withdrawal, and yet far greater anxiolytic and positive emotive effects. Why haven't they made it to market? Probably because they're too good.
Please read the rules ! don't promote illegal activity, we provide information for research purposes .....
Please read the rules ! don't promote illegal activity, we provide information for research purposes .....
Assyl Fartrate
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5-benzyl analogue of 14-methoxymetopon, a novel mu opioid analgesic with a reduced propensity to alter motor function...
Assyl Fartrate
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Williamson ether synthesis using DMSO as solvent and NaOH as base.
Assyl Fartrate
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Assyl Fartrate
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Great paper on Bentleys.
java
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Nickel-Catalyzed Intermolecular Insertion of Aryl Iodides to Nitriles: A Novel Method to Synthesize Arylketones
Jen-Chieh Hsieh, Yen-Chung Chen, An-Yi Cheng, and Hsiao-Chun Tseng
Org. Lett., Articles ASAP (As Soon As Publishable)
Publication Date (Web): February 14, 2012 (Letter)
DOI: 10.1021/ol300153f
Jen-Chieh Hsieh, Yen-Chung Chen, An-Yi Cheng, and Hsiao-Chun Tseng
Org. Lett., Articles ASAP (As Soon As Publishable)
Publication Date (Web): February 14, 2012 (Letter)
DOI: 10.1021/ol300153f
java
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.....We are forced to conclude, therefore, that the published synthesis2 is simply not viable.....Markondaiah Bekkam, Huaping Mo, and David E. Nichols*
In reference to the article,
A New Synthesis of Lysergic Acid
James B. Hendrickson* and Jian Wang
ORGANIC LETTERS 2004 Vol. 6, No. 1 3-5
A Reported “New Synthesis of Lysergic Acid” Yields Only The Derailment Product: Methyl 5-Methoxy-4,5-dihydroindolo[4,3-f, g]quinoline-9-carboxylate
Markondaiah Bekkam, Huaping Mo, and David E. Nichols*
Organic Letters
2010,vol.14, #1, pg.296-298
embezzler
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These are some old articles from the Journal of American Chemical Education. They are typically lab based demonstrations for the preparation of useful compounds
Preparation of methylamine
A chamber sulphuric acid plant for lecture demonstration
laboratory preparation of hydrofluoric acid
Preparation of constant boiling HBr
Preparation of acetamide
Oxidation of ammonia to nitric acid
methylamine from methanol and ammonia
Preparation of methylamine
A chamber sulphuric acid plant for lecture demonstration
laboratory preparation of hydrofluoric acid
Preparation of constant boiling HBr
Preparation of acetamide
Oxidation of ammonia to nitric acid
methylamine from methanol and ammonia
java
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Designer drugs: a medicinal chemistry perspective
F. Ivy Carroll, Anita H. Lewin, S. Wayne Mascarella, Herbert H. Seltzman,
and P. Anantha Reddy
Ann. N.Y. Acad. Sci.
xxxx (2011) 1–21 ?c 2011
DOI: 10.1111/j.1749-6632.2011.06199.x
Abstract
There are numerous medicinal chemistry reports in the literature describing the pharmacological properties of thousands of narcotics, stimulants, hallucinogens, sedative-hypnotic drugs, cannabinoids, and other psychoactive substances as well as synthetic methods for their preparations. This information, while essential for the advancement of science, has been used by clandestine chemists to manufacture and market an endless variety of analogs of so-called designer drugs. In this review, we describe how clandestine chemists used the principles of medicinal chemistry to design molecules, referred to as designer drugs, that elicit the effects of opioids, amphetamine and analogs, cannabinoids, and phencyclidine analogs while circumventing the law.
Keywords: controlled substances, designer drugs, medicinal chemistry, opioids, analgesics, amphetamines, cannabinoids, PCP, stimulants, hallucinogens