Vibrating_Lights
(Hive Bee)
10-25-01 01:17
No 228479
       where does the halogen go in the Bomb  Bookmark   

Where does the halogen go in the bomb with halosafrole and MeAm 		 
 
 
 
    goiterjoe
(Hive Addict)
10-25-01 01:26
No 228484
       Re: where does the halogen go in the Bomb  Bookmark   

It should pick up a hydrogen from the methylamine to produce the hydrochloric acid.
Sed quis custodiet ipsos custodes? 		 
 
 
 
    Vibrating_Lights
(Hive Bee)
10-25-01 02:30
No 228498
       Re: where does the halogen go in the Bomb  Bookmark   

If idio is used  then it will produce HI Correct.  How could you go about extracting it.  Will the post reaction A/B with NaOH convert the HI to NaI which could be extracted from the remaining polar mix with acetone after evaporation and saved for a later time. This reaction seems pretty efficent. 		 
 
 
 
    Bwiti
(Hive Addict)
10-25-01 07:42
No 228589
       Re: where does the halogen go in the Bomb  Bookmark   

"This reaction seems pretty efficent."

  I don't think it is. You'll get much better yields if you use an azide as the nucleophile, instead of ammonia or methylamine. All you need to do is reduce the safrole-azide with Mg or calcium. Total Synthesis 2 has all the info on this reaction that you need.cool
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