Vibrating_Lights
(Hive Addict)
05-10-03 07:33
No 432478
      Base Calculations  Bookmark   

What rules do i use to determine How much sodium carbonate to add to a mix of MeCN:H2O2:MeOH:Alkene to make the Ph 8 for an epoxidation?
VL_wink

Start thinking more like a chemist and less like a criminal
 
 
 
 
    Rhodium
(Chief Bee)
05-11-03 09:15
No 432628
      pH paper is the best method.  Bookmark   

pH paper is the best method.
 
 
 
 
    Vibrating_Lights
(Hive Addict)
05-17-03 08:10
No 433720
      I'M TRYING TO LEARN HERE  Bookmark   

Surely there is a way to calculate it before hand.  Whata gives.  I can't even think of where to look for such info.
Vl_

Start thinking more like a chemist and less like a criminal
 
 
 
 
    Megatherium
(Hive Bee)
05-17-03 08:40
No 433725
      pH calculations are only valid in aqueous...  Bookmark   

pH calculations are only valid in an aqueous medium (i.e. not in a acetonitrile / methanol mix).
 
 
 
 
    Rhodium
(Chief Bee)
05-17-03 13:21
No 433765
      pH in non-aqueous protic solutions  Bookmark   

Megatherium: That is not exactly true, you can make valid pH calculations in all protic solvents (such as methanol), not exclusively in water. However, you need to use a completely different set of variables than when doing it for aqueous solutions.

V_L: It's nice that you are trying to learn, but it is incredibly difficult to calculate beforehand what pH an aqueous mixture will have if you are adding several different solutes, as well as aubstances which aren't simple acids and bases. In this case, when it isn't even an aqueous solution, then you are really far out...