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Rhodium (Chief Bee) 01-26-04 07:46 No 484617 |
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Imines from alcohols in one pot. (Rated as: good read) |
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In Situ Oxidation-Imine Formation-Reduction Routes from Alcohols to Amines Leonie Blackburn and Richard J. K. Taylor Org. Lett. 3(11) 1637-1639 (2001) (https://www.rhodium.ws/pdf/alcohol2amin DOI:10.1021/ol015819b [image] Abstract Manganese dioxide is employed as an in situ oxidant for the one-pot conversion of alcohols into imines. In combination with polymersupported cyanoborohydride (PSCBH), a one-pot oxidation-imine formation-reduction sequence is reported. This procedure enables alcohols to be converted directly into both secondary and tertiary amines. The Hive - Clandestine Chemists Without Borders |
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