James
April 7th, 2002, 01:18 AM
This week on Kewl chemistry corner we will examine the action of ethanoic acid upon natrium hydrogen carbonate. The reaction produces Natrium acetate and unstable carbonic acid. Due to the formation and decomposition of the carbonic acid this reaction has found it's way into 'kewl' lore as a 'gas bomb'. The more valuable Natrium acetate is often completely overlook by these individuals.
<center>The Half-cells</center>
<table><tr><td>
NaHCO<sub>3</sub> + HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> -> NaC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> + H<sub>2</sub>CO<sub>3</sub>
Na<sup>+</sup>H<sup>+</sup>CO<sub>3</sub><sup>-2</sup> <=> Na<sup>+</sup> + H<sup>+</sup> + CO<sub>3</sub><sup>-2</sup>
H<sup>+</sup>C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> <=> H<sup>+</sup> + C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup>
Na<sup>+</sup> + C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> <=> Na<sup>+</sup>C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup>
2H<sup>+</sup> + CO<sub>3</sub><sup>-2</sup> <=> H<sup>+</sup><sub>2</sub>CO<sub>3</sub><sup>-2</sup>
</td><td> </td><td>
H<sub>2</sub>CO<sub>3</sub> <=> H<sub>2</sub>O + CO<sub>2</sub>
H<sup>+</sup><sub>2</sub>C<sup>+4</sup>O<sup>-2</sup><sub>3</sub> <=> 2H<sup>+</sup> + C<sup>+4</sup> + 3O<sup>-2</sup>
C<sup>+4</sup> + O<sub>2</sub><sup>-2</sup> <=> C<sup>+4</sup>O<sup>-2</sup><sub>2</sub>
2H<sup>+</sup> + O<sup>-2</sup> <=> H<sup>+</sup><sub>2</sub>O<sup>-2</sup>
</td></tr></table>
One significant use of the resulting natrium acetate is in the production of highly concentrate ethanoic acid. This is the kewl chemistry corner tune in next week.
<center>The Half-cells</center>
<table><tr><td>
NaHCO<sub>3</sub> + HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> -> NaC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> + H<sub>2</sub>CO<sub>3</sub>
Na<sup>+</sup>H<sup>+</sup>CO<sub>3</sub><sup>-2</sup> <=> Na<sup>+</sup> + H<sup>+</sup> + CO<sub>3</sub><sup>-2</sup>
H<sup>+</sup>C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> <=> H<sup>+</sup> + C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup>
Na<sup>+</sup> + C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> <=> Na<sup>+</sup>C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup>
2H<sup>+</sup> + CO<sub>3</sub><sup>-2</sup> <=> H<sup>+</sup><sub>2</sub>CO<sub>3</sub><sup>-2</sup>
</td><td> </td><td>
H<sub>2</sub>CO<sub>3</sub> <=> H<sub>2</sub>O + CO<sub>2</sub>
H<sup>+</sup><sub>2</sub>C<sup>+4</sup>O<sup>-2</sup><sub>3</sub> <=> 2H<sup>+</sup> + C<sup>+4</sup> + 3O<sup>-2</sup>
C<sup>+4</sup> + O<sub>2</sub><sup>-2</sup> <=> C<sup>+4</sup>O<sup>-2</sup><sub>2</sub>
2H<sup>+</sup> + O<sup>-2</sup> <=> H<sup>+</sup><sub>2</sub>O<sup>-2</sup>
</td></tr></table>
One significant use of the resulting natrium acetate is in the production of highly concentrate ethanoic acid. This is the kewl chemistry corner tune in next week.