News:

Registration doesn't require a real email.
Monero Donation Address: 897ESh4QoJgEytJueBPULziMDfNMToXkGMrvtUCJRo2NQRv2CXACHnmEzeMTkwQhnfcZsAc3ctXp6GsedhMfBv983rn5i84

Main Menu

Make Formic Acid and Hydroxylamine in one step!!

Started by foxy2, September 22, 2001, 01:42:00 AM

Previous topic - Next topic

0 Members and 1 Guest are viewing this topic.

Rhodium

Action of Mineral Acids on Primary Nitroparaffins
S. B. Lippincott & H. B. Hass

Industrial & Engineering Chemistry 31, 118-120 (1939)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/nitro2acid.pdf)

Abstract
Convenient and economical procedures have been developed for the preparation of acetic, propionic, butyric, and isobutyric acids in good yields from the corresponding primary nitroparaffins by refluxing them with 85 per cent sulfuric acid. Hydroxylamine acid sulfate is a by-product of the reaction. Propionohydroxamic acid has been prepared from 1-nitropropane and concentrated sulfuric acid in fair yield.
____ ___ __ _

As mentioned in

Post 216105

(lugh: "Caution!!!", Chemistry Discourse)


Ueber eine Verbindung von Nickelsulfat mit Hydroxylamin
Rudolf Uhlenhuth

Ann. Chem. 307, 332-334 (1899)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/hydroxylamine.freebase.pdf)