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Started by dildoque, August 13, 2001, 12:43:00 PM

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dildoque

PEA
August 13, 2001, 12:43:00 PM

http://www.ch.ic.ac.uk/local/projects/s_thipayang/synth.html



Reaction 3 looks interesting. Would it be possible to use methoxyphenol instead of indole ?

Rhodium

#1
August 13, 2001, 12:58:00 PM
In some instances perhaps. See the text

https://www.thevespiary.org/rhodium/Rhodium/chemistry/dmane.html

for more information on a related reagent. Could you find any other references on this reaction?

dildoque

#2
August 14, 2001, 12:28:00 PM
I found this :
https://www.thevespiary.org/rhodium/Rhodium/hive/hiveboard/picproxie_docs/000204216-file_cgbq.jpg" title="View this image">

Is there any kind of rearrangement to move the -CH2-CH2-NO2 in the right position ?
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