IBX Esters with Bleach!

[metanoid]

this is fantastic!

step 1. turn a 2-iodobenzoic acid ester into the corresponding  ibx ester with bleach

step 2. benzyl alcohol -> benzaldehyde 100%

step 3. lots and lots of other oxidations.

here are the gooodies.

https://www.thevespiary.org/rhodium/Rhodium/hive/hiveboard/picproxie_docs/000520388-ibx_bleach.pdf" target="_blank" title="Download this file">

[Rhodium]

Preparation and structure of 2-iodoxybenzoate esters: soluble and stable periodinane oxidizing reagents
V.V. Zhdankin, D.N. Litvinov, A.Y. Koposov, T. Luu, M.J. Ferguson, R. McDonald, R.R. Tykwinski
Chem. Commun.,(1), 106-107 (2004), DOI:

10.1039/b312961f

https://www.thevespiary.org/rhodium/Rhodium/hive/hiveboard/picproxie_docs/000520388-b312961f-s1.gif" target="_blank" title="View this image">

Abstract
Esters of 2-iodoxybenzoic acid (IBX-esters) are potentially valuable oxidizing reagents belonging to a new class of pentavalent iodine compounds with a pseudo benziodoxole structure.


Full Text: https://www.thevespiary.org/rhodium/Rhodium/hive/hiveboard/picproxie_docs/000520388-2004a-structure_preparation_2-iodoxybenzoate_esters.pdf" target="_blank" title="Download this file">

Supplementary Data (Microsoft Word format, 117 KB):

Synthetic and characterization data for all new compounds

(http://www.rsc.org/suppdata/cc/b3/b312961f/b312961f.doc)