Author Topic: Idea for MDP2P synthesis  (Read 2577 times)

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demorol

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Idea for MDP2P synthesis
« on: June 26, 2002, 08:22:00 PM »
While reading P2P synthesis from chloroacetone on Rhodium's site I came up with an idea for this synthesis.

1,3-benzodioxole + chloroacetone --> MDP2P

If it works with benzene I think it should work with 1,3-benzodioxole too. The only problem are the yields, which are kinda low with benzene. Any comments or suggestions?

Life without chemistry would be a mistake.

Trypstar

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Mn(III)
« Reply #1 on: June 26, 2002, 08:28:00 PM »
Or yould could also use the Mn(III) catalyzed version, but in both cases you'll also end up with the 2,3-methylenedioxy-P2P.

demorol

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2,3-MDP2P separation?
« Reply #2 on: June 26, 2002, 08:38:00 PM »
How can 2,3-MDP2P be separated from 3,4-MDP2P? Would a fractional vacuum distillation work? What is the boiling point of 2,3-MDP2P?

Life without chemistry would be a mistake.

El_Zorro

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If you read TSII, then you'd know that AlCL 3 ...
« Reply #3 on: June 26, 2002, 09:55:00 PM »
If you read TSII, then you'd know that AlCL3 tears the methylenedioxy ring all to shit.  The 1,3 benzodioxole+chloroacetone synth can never work.

Do not go gentle into that good night.  Rage, Rage, against the dying of the light.  --Dylan Thomas