Author Topic: Unknown Tryptamine?  (Read 10488 times)

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ClearLight

  • Guest
AKKK! Moron Mushroom Munchers!
« Reply #20 on: May 15, 2003, 01:13:00 PM »
To prevent your inadvertant deletion from the Gene Pool, I suggest the following.

  UTSFE on my username and read everything about TLC including the section on using the modified van-urk/salwoski reagents for identifying tryptamines. Over 150 tryptamines can be discriminated in that journal ref i posted.

  Get a GOOD 1200x microscope and learn how to do spore identification.  That is the ONLY reliable method for mushroom id.  Once you have the spore id'd.. (size, shape, color)  then you can compare it against the macroscopic properties of your fungus.

  The tlc gear you can ghetto up for about $10.00.  The reagents can be purchased from chem supply spots or auctions..

  Really no reason for gambling here.. you can easily use SCIENCE to find out the TRUTH!


foxy2

  • Guest
This sounds like Anxiety in disguise to me
« Reply #21 on: May 18, 2003, 01:16:00 AM »
This sounds like Anxiety in disguise to me

Jaded

  • Guest
<- 1st to know
« Reply #22 on: October 01, 2003, 11:39:00 AM »
Also again im not responsible for your mistakes eating these I JUST HAD A POST SAY THATS IMPOSSIBLE SO DONT ACT LIKE U KNEW ALL ALONG THATS NUTS
these grow on cow dirt...***but some supposebly are diffrent but i dont think they r so thats why i said the 1st description cauze its much easier and the spore print can be white, purple, or black.

Vitus_Verdegast

  • Guest
Hmm...
« Reply #23 on: October 02, 2003, 06:02:00 PM »
You know what?
Send some samples of your mushroom to Jochen Gartz.

While you are in the cow pastures:
For psilocybe semilanceata (for all you temp climate people  ;) ):

I. Go buy a mushroom field manual before picking.

II. P. semilanceata is easily recognized, common in cow pastures, does *not* grow directly on cow shit, It is brown in appearance when wet, yellowish when dry from sun, and have always purpleblack sporeprints.

III. Don't eat any mushrooms if you are not 100% sure of their identity. The class know as 'little brown mushrooms' (LBM's) is gigantic and *a lot* of them grow in cow pastures.


dennis_pro

  • Guest
what is 'aeruginascin'
« Reply #24 on: October 03, 2003, 12:05:00 AM »
I've readed

article

(http://www.eleusis.ws/en/articles/vel-gartzinocybe.shtml) about psychoactive mushroom Inocybe Aeruginascens: "It shoul be noted that results from the analysis of the mushrooms indicated the presence of a previously unknown alkaloid, which was named aeruginascin (Gartz, 1987, 1989). The structure of aeruginascin must be very similar to those of baeocystin and psilocybin and the levels of concentration of aeruginascin found in the mushrooms are comparable to those of psilocybin and baeocystin (Gartz, 1989)."

Anybody knows anything about this alkaloid? Structure? Properties?


Rhodium

  • Guest
The structure of aeruginascin is still unknown
« Reply #25 on: October 03, 2003, 06:36:00 AM »

plasmaxs

  • Guest
antipsychotic medication?
« Reply #26 on: October 08, 2003, 01:22:00 PM »
jaded do you say your antipsychotic medication is marijuana?
if so
This would not be my medication of choice people with mental dissorders including underlying ones which may not have been noticed yet more often worsons the problem/s. iam one of these people trust me, get some help from someone who can perscribe drugs then u might get a real antipsychotic like rispeidone.    
on the mushroom case the mushroom which could be a posserbilerty is Inocybe corydalina var. erinaceomorpha pic at

http://www.mushroomjohn.com/species12a.htm


there are a few other Inocybe's at the site
allthough like someone said spore identification  is the onley real way of finding out.

Jaded

  • Guest
http://www.grzyby.pl/coprinus-site-Kees-Uljee/s...
« Reply #27 on: November 13, 2003, 05:08:00 AM »

http://www.grzyby.pl/coprinus-site-Kees-Uljee/species/pellucid.htm



To be sure to get the right kind use this link because the gill color and size can be diffrent. I had posted this link b4 and im not a mycologist so i dont know discripts only the dried out shrooms he had =)

And i was only posting the description so someone could run tests WITHOUT eating them that was the idea of the post.

Jaded

  • Guest
yo
« Reply #28 on: November 30, 2003, 11:04:00 PM »

Psi_Locybe

  • Guest
This is not a particularly meaningful subject lin.
« Reply #29 on: January 20, 2004, 12:37:00 AM »
>***I AM NOT RESPONSIBLE FOR ANYTHING THAT IS DONE BECAUSE
>OF THIS POSE.  IF YOU THINK OTHERWISE THEN PLEASE REFRAIN
>YOURSELF FROM READING THIS POST.***

Oh, trust me dawg - it's far, FAR more likely that something horrific will come of someone being foolish enough to believe the crap in my post, than someone being foolish enough to believe the crap in your post.

I disavow all responsibility for your actions.

>My questions are is there anyway that a test can be done
>to find out the chemical make up of this drug?

 "A" test?  ***"A"*** test?

 The fact that you know even less about ghetto analytical chemistry than, yes, even I, fills me with a fear and dread unparalleled since the time my friend slit my throat, and I was grilling, dead, as God bitched me out for being a freakin' hippie.

Again, do I reiterate my disclaimer.  No, there is unfortunately not "a test which will tell you the chemical makeup."  There are a few techniques which will allow you to say "it is itself, and these are its properties."  If it was a simple hydrocarbon, I'd say brominate the fucking thing and count carbon.  You can probably still do that with it's pieces, once you blast a chunk to smithereens on the molecular level, and isolate "smithereens" from breakdown - i.e. "one compound believed to be a formerly-indolic clump" in one vial, "ethane" over here...

...it still won't tell you NEARLY as much as if it were just a nice, simple hydrocarbon which DIDN'T have, say, a tendancy to blast itself apart under most conditions of substitution, or, say, an amine which likes to halogenate more than it reasonably should, or...

...sorry, I'm rambling.

-------------------------------------------
Starting point :

...get your ass about 1/2 ton of these shrooms, and a giant freaking boiler.  I am, quite literally, not shitting you.  Mind you, this is probably felonious as fuck.

Step 2 :

Base out the alkaloids.  Dose yourself.  Still the same issues?  Are you *sure* it's not just psychosomatic - trips can do that, y'know?  If you *still* want to proceed...

Step 3:

 Take a few pounds of yon alkaloids.  Bust a little column chromatography under the blacklight. 

"I know the drug is a tryptamine..."

Are you sure...?

POSITIVE???

Counterexample - sodium 2acetoxybenzoate is an a2 norepinephrine antagonist.  As such, it is theoretically quite feasible that Na2AOB could *drastically* change an existing tryptamine-based experience, via the increased noradrenaline release, resulting in a potentially-negative, more potent tryptaminoid hallucinogenic experience.

I say this only because (a) I'm a fucking idiot, and (b) you appear to know even less than I do - 2acetoxybenzoic acid isn't a tryptamine, it's asprin.

...but... *IF* you still think you're sure...

...store the different glowing bands in different bottles, naturally, as you engage in a little column chromatography.  *IF* you're right about the matter being tryptaminic, it is now in *one* of those bottles.

Step 4 :

Eat each bottle, one at a time.  Note variances in nuance.  Also, please be sane enough not to eat the whole bottle at once - this is for two reasons...

a) People munchin' the base of a full-fledged 2000 lbs of shrooms make very, very poor chemists for quite some time, and...

b) You need to save some for analysis.

...also, have your friends run double-blinds on your bioassay.

Step 5 :

Look up "boiling point constant h2o" on either TFSE or AFSE.  This should tell you exactly how to determine the mol. wt. of your substance.  *IF* you are correct, and it's a simple tryptamine, THIS WILL MAKE "WHAT-THE-FUCK-IT-IS" **SO** much easier to figure out.  If it's "not quite a mild variance" - i.e., 'truly unknown compound,' then you will know that compound X has a mol. wt. of 'n', by tautology.

Step 6 :

"I know the drug is a tryptamine..."

Heh - still sure?

Well...

...in that case, run the Keller.  If I named the wrong test, I'm sure someone will correct me.  In fact, since I haven't read the whole thread, I'm sure someone has.  Note the color for posterity...

Step 7 :

...you should have already tested the mp of the base, HCl, acetate, and any other acids you can get your hands on by now... record them *well* - as you record all other data.

Step 8 :

Check the literature - has anyone recorded anything with an identical crystalline structure (HCl, C2O2H4, CO2H2, etc), mp (HCl, C2O2H4, CO2H2, base, etc), reaction to the Keller test, mol. wt., etc, etc...

...if so, you *might* know what it is.  Maybe.  One never can be QUITE sure...

If not, you have "Compound X, mol wt n, mp (salt 1) (salt 2) (etc) bp (salt 1) (salt 2) (etc) notes : Keller test ___, flourescence noted under UV, and maybe some other notes."

This is enough for you to name a theoretically-completely-new-compound, earning your place in the annals of science for ages innumerable.  It also gives you a JadedMerk ref for your theoretically-completely-new-compound.

...and if you're really, REALLY bright, you can think up potentially valid structures based on the theorized nucleus and the mol. wt. and test them based on the properties; methoxybenzene and parahydroxymethylbenzene, for instance, have a different reaction to MeI.

Have fun.  Welcome to science, kid... and above all, don't listen to this idiot - yeah, the one typing the post, find someone who knows what they're doing...