Review: Base-Catalyzed Hydroamination of Olefins: An Environmentally Friendly Route to AminesAdvanced Synthesis & Catalysis, 344(, 795-813 (2002)
(
https://www.thevespiary.org/rhodium/Rhodium/pdf/base-cat.hydroamination.review.pdf)
DOI:
10.1002/1615-4169(200209)344:83.0.CO;2-Q
A Base-Catalyzed Domino-Isomerization–Hydroamination Reaction – New Synthetic Route to AmphetaminesDOI:
10.1016/S0040-4020(00)00436-1
Tetrahedron 56(29), 5157-5162 (2000)
(
https://www.thevespiary.org/rhodium/Rhodium/pdf/hydroamination.allylbenzene2amphetamines.pdf)
Post 271694
(foxy2: "Re: here it is: direct amination of allylbenzene", Chemistry Discourse)Post 465442
(Rhodium: "Hydroamination Route to Amphetamines", Chemistry Discourse)
Amphetamines and phenyl-2-propanones from 1-phenylpropyne and aminesNone
(
https://www.thevespiary.org/rhodium/Rhodium/pdf/catalytic.hydroamination.alkynes.pdf)
Hydroamination of Cinnamylalcohol
(
http://www.unibas.ch/mdpi/ecsoc-3/a0025/a0025.htm)
Photoinduced amination of styrenes to phtalimide-protected phenethylaminesPost 429395
(Rhodium: "Photophtalimidation of styrenes to PEAs", Serious Chemistry)
An Ammonia Equivalent for the Dimethyltitanocene-Catalyzed Intermolecular Hydroamination of AlkynesPost 434626
(ChemisTris: "Dimethyltitanocene cat. hydroamination of alkynes", Novel Discourse)Org. Lett. 2(13), 1935-1937 (2000)
(
https://www.thevespiary.org/rhodium/Rhodium/pdf/dimethyltitanocene-hydroamination.pdf)
DOI:
10.1021/ol006011e
Synthesis of allylic amines through the palladium-catalyzed hydroamination of allenesTetrahedron Letters 36(22), 3857-3860 (1995)
(
https://www.thevespiary.org/rhodium/Rhodium/pdf/hydroamination.allenes.pdf)
DOI:
10.1016/0040-4039(95)00656-W
Riken Review No. 42, pp 53-56 (2001)
(
https://www.thevespiary.org/rhodium/Rhodium/pdf/ruthenium.hydroamination.1-alkynes.pdf)
Ruthenium complexes that efficiently catalyze hydration and hydroamination of 1-alkynes have been found. The hydration described here is the first example of anti-Markovnikov regioselectivity to produce aldehydes. A mechanism involving Ru(IV)-hydride-vinylidene intermediate is proposed. A highly practical catalytic hydroamination method has also been developed which was applied to synthesis of nitrogen containing heterocycles.