Simple cooking culinary arts style teaches that alcohol can be cooked out of any dish containing alcohol without completely dehydrating the dish....so theoretically yes...the alky will boil off before the majority of h2o is boiled off.
And without knowing my ass from a hole in the ground....hehehe
so take it with a grain of salt..meth preferably
Distillation of heavier aliphatic hydrocarbons(AHC) in h2o will push the volatile AHC over first.
Alcohol evaps at a greater rate than h2o so I would think it too could be pushed over first during distillation leaving the non-volatile h2o behind.
I could be wrong here and I'm sure I'll hear about it if so.
I only offer my view in light of what wizardx posted is weigh over my head.....anvilstyle!
No Offense WizX...but that was all pure chemistry what you posted and something US tweekers are needing to get on the ball with here real quick.
In other words....thank you for that chart!
Right on time in my book!