The Vespiary

The Hive => Methods Discourse => Topic started by: chinone on September 24, 2002, 09:10:00 AM

Title: Sodium Triacetoxyborohydride Reductive Amination
Post by: chinone on September 24, 2002, 09:10:00 AM
Has anyone tried this? If so what were the results and conditions used?
Title: yes. daily between 8:30 and 9:00 am. why ask?
Post by: Organikum on September 24, 2002, 11:14:00 AM

http://www.callery.com/pdf/bulletin/calselect_stab.pdf (http://www.callery.com/pdf/bulletin/calselect_stab.pdf)



under "applications" is listed what this compound maybe used for.

ORGY
~ Love is the law, love under will. ~
Title: http://www.rhodium.ws/pdf/sodium.
Post by: Rhodium on September 24, 2002, 05:13:00 PM

https://www.thevespiary.org/rhodium/Rhodium/pdf/sodium.triacetoxyborohydride.pdf (https://www.thevespiary.org/rhodium/Rhodium/pdf/sodium.triacetoxyborohydride.pdf)

Title: Triacetoxy has been used, and was found to give ...
Post by: slappy on October 02, 2002, 07:20:00 PM
Triacetoxy has been used, and was found to give very favorable results.

1 eq. NaBH(OAc)3 in 47.5/47.5/5 Dichloroethane(DCE)/THF/AcOH and amine freebase.