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The Hive => Chemistry Discourse => Topic started by: Vibrating_Lights on June 02, 2002, 06:06:00 PM

Title: Riley oxidation
Post by: Vibrating_Lights on June 02, 2002, 06:06:00 PM

H.L riley et al., J. Chem. Soc.1932,1875
Oxidation of active Methylene groups to carbonyl compounds
Selenium Dioxide (Riley Oxidation)
          White crystalline solid, mp 340°C, very poisonous
          Selenium metal is the by-product
          Solvents = dioxane, HOAc/Ac2O, H2O

         
(http://www.chem.uh.edu/Courses/Thummel/Chem6352/Ch12/ Title: Here it is
Post by: Elementary on June 02, 2002, 06:42:00 PM

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