Author Topic: Hydroamination routes to Amphetamines & PEAs  (Read 2496 times)

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Rhodium

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Hydroamination routes to Amphetamines & PEAs
« on: October 18, 2003, 10:42:00 AM »
Review: Base-Catalyzed Hydroamination of Olefins: An Environmentally Friendly Route to Amines

Advanced Synthesis & Catalysis, 344(8), 795-813 (2002)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/base-cat.hydroamination.review.pdf)
DOI:

10.1002/1615-4169(200209)344:83.0.CO;2-Q





A Base-Catalyzed Domino-Isomerization–Hydroamination Reaction – New Synthetic Route to Amphetamines
DOI:

10.1016/S0040-4020(00)00436-1


Tetrahedron 56(29), 5157-5162 (2000)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/hydroamination.allylbenzene2amphetamines.pdf)

Post 271694

(foxy2: "Re: here it is: direct amination of allylbenzene", Chemistry Discourse)

Post 465442

(Rhodium: "Hydroamination Route to Amphetamines", Chemistry Discourse)




Amphetamines and phenyl-2-propanones from 1-phenylpropyne and amines

None

(https://www.thevespiary.org/rhodium/Rhodium/pdf/catalytic.hydroamination.alkynes.pdf)





Hydroamination of Cinnamylalcohol

(http://www.unibas.ch/mdpi/ecsoc-3/a0025/a0025.htm)





Photoinduced amination of styrenes to phtalimide-protected phenethylamines

Post 429395

(Rhodium: "Photophtalimidation of styrenes to PEAs", Serious Chemistry)






An Ammonia Equivalent for the Dimethyltitanocene-Catalyzed Intermolecular Hydroamination of Alkynes

Post 434626

(ChemisTris: "Dimethyltitanocene cat. hydroamination of alkynes", Novel Discourse)

Org. Lett. 2(13), 1935-1937 (2000)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/dimethyltitanocene-hydroamination.pdf)
DOI:

10.1021/ol006011e







Synthesis of allylic amines through the palladium-catalyzed hydroamination of allenes

Tetrahedron Letters 36(22), 3857-3860 (1995)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/hydroamination.allenes.pdf)
DOI:

10.1016/0040-4039(95)00656-W








Riken Review No. 42, pp 53-56 (2001)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/ruthenium.hydroamination.1-alkynes.pdf)

Ruthenium complexes that efficiently catalyze hydration and hydroamination of 1-alkynes have been found. The hydration described here is the first example of anti-Markovnikov regioselectivity to produce aldehydes. A mechanism involving Ru(IV)-hydride-vinylidene intermediate is proposed. A highly practical catalytic hydroamination method has also been developed which was applied to synthesis of nitrogen containing heterocycles.