The Vespiary

The Hive => Newbee Forum => Topic started by: GC_MS on November 09, 2003, 08:04:00 PM

Title: Aryl Halides to Thiophenols using Thiourea
Post by: GC_MS on November 09, 2003, 08:04:00 PM
I have a question concerning the following page on Rh's page:

https://www.thevespiary.org/rhodium/Rhodium/chemistry/thiophenol.thiourea.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/thiophenol.thiourea.html)



The patent describes the reaction between a aryl halide and thiourea to yield a thiophenol after addition of aqueous NaOH. My question: what is the intermediate of the reaction between the aryl halide and thiourea? Is it the thiouronium salt or another compound?

Title: Post 433179
Post by: imp on November 10, 2003, 04:21:00 AM

Post 433179 (https://www.thevespiary.org/talk/index.php?topic=7181.msg43317900#msg43317900)

(catastrophe: "Aralkyl halides to Thiols", Chemistry Discourse)