The Vespiary

The Hive => Methods Discourse => Topic started by: demorol on June 06, 2004, 02:20:00 PM

Title: Protection & Deprotection of various funct. groups
Post by: demorol on June 06, 2004, 02:20:00 PM

Protection (and Deprotection) of Functional Groups in Organic Synthesis by Heterogenous Catalysis
Giovanni Sartori, Roberto Ballini, Franca Bigi, Giovanna Bosica, Raimondo Maggi, and Paolo Righi

Chem. Rev. 2004, 104, 199-250

(https://www.thevespiary.org/rhodium/Rhodium/hive/hiveboard/picproxie_imgs/pdf.gif)

Contents

1.   Introduction
2.   Hydroxy Protecting Groups
   2.1.   Esters
      2.1.1.   Protection
      2.1.2.   Deprotection
   2.2.   Silyl Ethers
      2.2.1.   Protection
      2.2.2.   Deprotection
   2.3.   Alkoxyalkyl Ethers
      2.3.1.   Protection as THP Ethers
      2.3.2.   Protection as Other Alkoxyalkyl Ethers
      2.3.3.   Deprotection
   2.4.   Tosylates
   2.5.   Selective Protection of Polyfunctional Compounds
   2.6.   Selective Deprotection of Polyprotected Compounds
   2.7.   Redox Deprotections
3.   Thiol Protecting Groups
4.   Carboxy Protecting Groups
   4.1.   Protection
   4.2.   Deprotection
5.   Carbonyl Protecting Groups
   5.1.   Acetals
      5.1.1.   Protection
      5.1.2.   Deprotection
   5.2.   Dithioacetals
      5.2.1.   Protection
      5.2.2.   Deprotection
   5.3.   1,3-Oxathiolanes
   5.4.   1,1-Diacetates (Acylals)
      5.4.1.   Protection
      5.4.2.   Deprotection
   5.5.   Nitrogenous Derivatives
      5.5.1.   Protection
      5.5.2.   Deprotection
6.   Amino Protecting Groups
   6.1.   Protection
   6.2.   Deprotection
8.   Acknowledgments
9.   Abbreviations
10. References

Title: Book Protective groups
Post by: Chimitant on June 06, 2004, 11:44:00 PM

I recently downloaded a DJVU copy of a book called "Protective groups in organic synthesis" (Greene & Wutz). It has 473 pages and the following chapters:

1. The role of protective groups in organic synthesis
2. Protection for the hydroxylgroup, including 1,2- and 1,3-diols
3. Protection for phenols and catechols
4. Protection for the carbonyl group
5. Protection for the carboxyl group
6. Protection for the thiol group
7. Protection for the amino group
8. Reactivities, reagents and reactivity charts

Unfortunately, I lost the exact adress. I tried to find it back but the pages were not accesible. The adress:

http://chemister.fannet.ru/Download/download.htm (http://chemister.fannet.ru/Download/download.htm)

Title: Chemister's site
Post by: murmur on June 07, 2004, 09:05:00 PM

Unfortunately, I lost the exact adress. I tried to find it back but the pages were not accesible
This site was closed.
New address:

http://www.chemister.da.ru (http://www.chemister.da.ru)

Title: Found link back
Post by: Chimitant on June 08, 2004, 05:14:00 PM

Just by going to the adress murmur gave.... Other (organic) chembooks ca be found as well so I gave the general link. Number 48 is the book I was referring to.

http://rzv073.rz.tu-bs.de/bib/dir1/Books/Chembooks/Mechanizms/mechanizms.htm (http://rzv073.rz.tu-bs.de/bib/dir1/Books/Chembooks/Mechanizms/mechanizms.htm)