The Vespiary

The Hive => Methods Discourse => Topic started by: cheeseboy on March 18, 2002, 04:37:00 PM

Title: Dry HCl
Post by: cheeseboy on March 18, 2002, 04:37:00 PM
Why can't HCl acid be dried under silicagel or epsom salts? Is it becuase of azeotrope qualities of the water in the acid, which would mean that drying, or taking away some water out of the acid would just steal the acid in equal proportions as well? Cheese tried drying some HCl with a silica gel teabag and didn't really know what happened. It definatley adsobred some H2O/.

Cheeseboy-a whiteboy with Soul Like a black guy without soul
May The Source Bee With You Always.
Title: Re: Dry HCl
Post by: PrimoPyro on March 18, 2002, 04:42:00 PM
Pure HCl is a gas.

Vivent Longtemps La Ruche!
Title: Re: Dry HCl
Post by: cheeseboy on March 18, 2002, 04:49:00 PM
Ahhh, Thanks Pyro, now pls go and answer my other post regarding epoxid rearrangment with sulphuric acid. Thanks again.. :)  ;D

Cheeseboy-a whiteboy with Soul Like a black guy without soul
May The Source Bee With You Always.
Title: Re: Dry HCl
Post by: Brazilian_Bee on March 18, 2002, 05:29:00 PM
Yes, but is important to remember that when you produce HCl, you also produce heat i.e. you may carry some H2O along with it...
So, What I do is to have a condenser to allow H2O to flow back to the HCl/NaCl vessel...
:)  :)  :)
Title: Re: Dry HCl
Post by: terbium on March 18, 2002, 08:00:00 PM
Why can't HCl acid be dried under silicagel or epsom salts?
So, I think that the question is: why can't silica gel or magnesium sulfate be added to hydrochloric acid to absorb the water and liberate HCl gas?

I think a good answer is: because HCl gas likes water even more than silica gel or anhydrous magnesium sulfate.
Title: Re: Dry HCl
Post by: Argox on March 19, 2002, 03:45:00 AM
Rhodium's page has an excellent write-up about making dry HCl gas. 

(Couldn't resist)

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