Author Topic: Compilation of Acid Reagents  (Read 4417 times)

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Aurelius

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Compilation of Acid Reagents
« on: February 24, 2004, 01:51:00 AM »
Compilation of Acid Reagents

General Chemistry on Acid-Base theory

Post 204510 (missing)

(Rhodium: "Hofmann Acidity Scale (Funny)", General Discourse)

Post 445267 (missing)

(Aurelius: "Conjugate Acid-Bases and Their Relative Strengths", Chemistry Discourse)

Post 445288

(Aurelius: "Acid-Base Concepts", Chemistry Discourse)

Post 445301 (missing)

(Aurelius: "More acid-base concept chemistry", Chemistry Discourse)

Post 445317

(Aurelius: "Relative Strengths of Acids and Bases", Chemistry Discourse)

Post 445416

(Aurelius: "Acid-Base Charts", Chemistry Discourse)

Post 445436

(Aurelius: "Amphiprotism", Chemistry Discourse)

Post 445485

(Aurelius: "The Leveling Effect", Chemistry Discourse)

Post 445654 (missing)

(Aurelius: "Neutralization Reactions", Chemistry Discourse)

Post 445659 (missing)

(Aurelius: "Preparing Weak Acids from Salts and Strong Acids", Chemistry Discourse)

Post 445667

(Aurelius: "Hydrolysis Reactions", Chemistry Discourse)

Post 445692

(Aurelius: "Hydrolysis of Salts, Indicators and Buffers", Chemistry Discourse)

Post 445735

(Aurelius: "Structure and Its Effect Upon Acidity and Basicity", Chemistry Discourse)

Post 445752

(Aurelius: "Electronegativity, Acidity, Basicity and Trends", Chemistry Discourse)

Post 445868

(Aurelius: "The Hydrogen Halide Problem", Chemistry Discourse)

Post 445880

(Aurelius: "Acidity, Basicity and Ion Size", Chemistry Discourse)

Post 445933

(Aurelius: "Lewis Concept of Acidity and Basicity", Chemistry Discourse)


Physical data for all acids listed below can be found here.

Post 445906 (missing)

(Aurelius: "Acid Reagents Physical Properties", Chemistry Discourse)


Pka's of acids in water

http://www.stanford.edu/~travisw/pkas.pdf



Common Buffer Systems

http://ptcl.chem.ox.ac.uk/MSDS/buffers.html



General Methods for the synthesis of carboxylic acids:

Post 446181

(ChemisTris: "Mathews’ rxn(MW): carboxylic acids from nitriles", Chemistry Discourse)


HCl acid

Post 76013

(PolytheneSam: "Re: bromosafrole", Novel Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/hclgas.argox.html


https://www.thevespiary.org/rhodium/Rhodium/chemistry/hcl-gas.html



HI acid

Post 288929 (missing)

(Rhodium: "Hydriodic Acid From Pinene and Iodine", Stimulants)

Post 271993

(Argox: "Hydriodic Acid--Step by Step Write-Up", Stimulants)

see also: 

https://www.thevespiary.org/rhodium/Rhodium/chemistry/hydriodic.argox.html


Post 318864

(3base: "aq.HBr/HI from KBr/KI & tartaric acid", Novel Discourse)

Post 216544 (missing)

(Stonium: "Re: Shelf life of Hydroidic Acid ?", Newbee Forum)

Post 381437

(Rhodium: "Electrolytic HI", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/hydriodic.html


Post 398185

(Aurelius: "HI acid via tetralin/decalin", Methods Discourse)

Post 398187

(Aurelius: "HI acid via ascorbic acid and iodine", Methods Discourse)

Post 398198

(Aurelius: "Preparation of Pure Anhydrous HI in GAA", Methods Discourse)


HBr acid

Post 318864

(3base: "aq.HBr/HI from KBr/KI & tartaric acid", Novel Discourse)

Post 76013

(PolytheneSam: "Re: bromosafrole", Novel Discourse)

Post 381399

(PolytheneSam: "Electrolytic HBr", Chemistry Discourse)

Post 191676 (missing)

(abc123: "HBr gas?", Chemistry Discourse)


HF acid

HNO3

Post 76013

(PolytheneSam: "Re: bromosafrole", Novel Discourse)

Post 398201

(Aurelius: "100% Nitric Acid", Methods Discourse)

Post 398202

(Aurelius: "Preparation of Nitric Acid", Methods Discourse)

Post 398207

(Aurelius: "Preparation of Anhydrous Nitric acid in DCM", Methods Discourse)


H2S acid

Post 328633 (missing)

(lugh: "H2S", General Discourse)


HCN

Acetic Acid

Acetic Anhydride

Post 506730

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)

Post 462958

(Rhodium: "Na-Acetate + Na-Pyrosulfate -> Acetic Anhydride", Novel Discourse)

Post 247630 (missing)

(terbium: "Re: Acetic Anhydride", Chemicals & Equipment)

Post 216197

(Antoncho: "A completely OTC ;) acetic anhydride synthesis", Chemistry Discourse)

Post 391980

(BillyBoy: "From Ketene", Novel Discourse)

Post 391938

(Mountain_Girl: "AA from Acetaldehyde", Novel Discourse)

Post 274280

(foxy2: "Re: first encouraging ketenelamp experiment", Methods Discourse)

Post 98307 (missing)

(Stik E. Fingers: "Acetic anhydride from acetic acid and a salt", Chemistry Discourse)

Post 162355 (missing)

(drone 342: "Acetic Anhydride---again", Chemicals & Equipment)

http://www.orgsyn.org/orgsyn/prep.asp?prep=cv1p0330


https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html


Post 171900 (missing)

(Cheapskate: "Acetic Anhydride---again", Chemicals & Equipment)

Post 470665

(psyloxy: "acetic / propionic anhydride from NaO(Me)Ac + TsCl", Chemistry Discourse)



Acetyl Chloride

Post 506730

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html



Carbonic Acid

ChloroAcetic Acid

https://www.thevespiary.org/rhodium/Rhodium/chemistry/chloroacetic.html



Chlorosulfonic Acid

Post 311279 (missing)

(foxy2: "chlorosulfonic acid", Chemistry Discourse)


Acetone Dicarboxylic Acid

http://www.orgsyn.org/orgsyn/orgsyn/prepcontent.asp?print=1&showprint=1&prep=cv1p0010



Anthranilic acid

Post 413466

(pHarmacist: "Two Methods for the Preparation of Phthalimide", Novel Discourse)

Post 108807

(dormouse: "Anthranilic acid from phthalimide using OTC sodiumhypochlorite solution  -Methaco(s)m", Novel Discourse)

Post 108859 (missing)

(dormouse: "Anthranlic acid a la Cheapskate  -Cheapskate", Novel Discourse)


Cinnamic Acid

Post 501647

(Rhodium: "Cinnamic Acids from Malonic acid/Benzaldehyde", Novel Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/cinnamic.txt



Citric acid

https://www.thevespiary.org/rhodium/Rhodium/chemistry/citricacid.txt



MeO substituted Acids

3,4-Dimethoxyphenylpyruvic Acid

Post 413165

(Rhodium: "Old MDPEA synthesis", Methods Discourse)
 
3,4-Dimethoxyphenylacetic Acid

Post 413165

(Rhodium: "Old MDPEA synthesis", Methods Discourse)
 
3,4-Methylenedioxycinnamic Acid

Post 413165

(Rhodium: "Old MDPEA synthesis", Methods Discourse)


Diphenylacetic acid

https://www.thevespiary.org/rhodium/Rhodium/pdf/substituted.diphenylacetic.pdf


Post 398785 (missing)

(Aurelius: "Preparation of Diphenylacetic acid", General Discourse)


Formic acid

Post 449230

(abolt: "Formic acid S.G.", Chemicals & Equipment)

Post 216070

(foxy2: "Make Formic Acid and Hydroxylamine in one step!!", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/formic.acid.html


Post 468940

(ning: "Oxalic and formic acid  from sawdust", Novel Discourse)


Hydrogen Carbonate Salts(acidic) HCO3-

Hypophosphorus acid (H2PO2)

Post 246126 (missing)

(lugh: "Hypophosphoric Acid Synthesis", Chemicals & Equipment)


Lysergic Acids and Related Acids

Post 403852

(pHarmacist: "Synthesis of Lysergic Acid Derivatives", Tryptamine Chemistry)


Mandelic acid

Post 479855

(dioulasso: "Substituted Mandelic acids", Chemistry Discourse)

Post 504013

(starlight: "some interesting mandelic acid patents", Chemistry Discourse)

Post 248176 (missing)

(timsong: "Mandelic Acid Synth", Stimulants)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/mandelic.html


Post 400338 (missing)

(Rhodium: "Resolution of dl-Ephedrine", Stimulants)


Nitrous Acid

Oxalic Acid

https://www.thevespiary.org/rhodium/Rhodium/chemistry/formic.acid.html


http://www.geocities.com/Baja/Canyon/2609/cleaners.html


Post 468940

(ning: "Oxalic and formic acid  from sawdust", Novel Discourse)

Post 473728

(ning: "Improved Oxalic Acid Extraction", Chemicals & Equipment)


Oxalyl chloride (oxalic chloride)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/oxalylchloride.html



Para-Toluene Sulfonic Acid (p-Tosic acid)
 

Post 505622

(psyloxy: "H2SO4 + toluene --> p-tosic acid", Chemistry Discourse)

Post 288713

(Chromic: "Getting higher yields with p-tosic acid", Methods Discourse)

Post 389646

(Antoncho: "Toluenesulfonic acid - tips and tricks.", Methods Discourse)

Post 261000

(Chromic: "p-toluenesulfonic acid", Chemistry Discourse)

Post 261199

(terbium: "Re: p-toluenesulfonic acid", Chemistry Discourse)

Post 273447

(Rhodium: "Re: p-toluenesulfonic acid", Chemistry Discourse)

Post 389646

(Antoncho: "Toluenesulfonic acid - tips and tricks.", Methods Discourse)


Perchloric Acid

Phenyl Acetic Acid

From Cinnamic Acid:

Post 509760

(Rhodium: "Cinnamaldehyde -Oxone-> Phenylacetic Acid", Chemistry Discourse)
(40% yields w/oxone in aq. acetone!)

Post 413520

(Aurelius: "phenylacetic acid", Novel Discourse)

phenyl acetic acid patents

Post 370541

(Lilienthal: "We have a patent markup...", Novel Discourse)

phenylacetic acid from ethylbenzene

Post 219903 (missing)

(Bwiti: "Phenylacetic Acid from Ethylbenzene", Methods Discourse)

Post 219657 (missing)

(obituary: "Re: ethylbenzene", General Discourse)

?

Post 203572

(obituary: "phenylacetic acid", Novel Discourse)

Post 413520

(Aurelius: "phenylacetic acid", Novel Discourse)

Post 108296

(dormouse: "phenylacetic acid  -Scooby Doo", Novel Discourse)

Post 412602 (missing)

(Aurelius: "PhenylAcetic Acid", Stimulants)


Phenylglyoxylic Acid

Post 500342

(Rhodium: "Phenylglyoxylic Acid from Styrene", Chemistry Discourse)


PolyPhosphoric Acid

Post 398338

(Aurelius: "repost", Methods Discourse)


Propionic Acid

Post 449395

(Aurelius: "Propionic acid", Chemistry Discourse)

Post 463633

(psyloxy: "propionic acid from n-propanol / HNO3 - 84% yield", Chemistry Discourse)

Post 461624

(Antoncho: "Propionic acid from MEK - let's find it out!", Novel Discourse)

Post 461856

(roger2003: "Old Ways - Mabe, they are helpful", Novel Discourse)

Post 463793

(Rhodium: "Propionic Acid from Methyl Ethyl Ketone/Ca(OCl)2", Novel Discourse)

Post 463795

(roger2003: "Propionic Acid from Propanol", Novel Discourse)

Post 463783

(roger2003: "Propionic acid from MEK", Novel Discourse)


Propionic Anhydride

Post 506730

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)

Post 470665

(psyloxy: "acetic / propionic anhydride from NaO(Me)Ac + TsCl", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html



Propionyl Chloride

Post 506730

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)


Pyruvic Acid

Post 463560

(roger2003: "Pyruvic Acid", Serious Chemistry)

Post 384565 (missing)

(cthulhujr: "Pyruvic Acid Synthesis and 24%", Stimulants)


Sulfuric Acid

Sulfurous Acid

Per- Acids

In General:

Post 415088

(GC_MS: "The synthesis of peracids", Chemistry Discourse)


m-Chloroperbenzoic acid

https://www.thevespiary.org/rhodium/Rhodium/pdf/mcpba.pdf


https://www.thevespiary.org/rhodium/Rhodium/pdf/m-cpba.pdf




acetic

Post 413717

(GC_MS: "Determination of peracid content", Chemistry Discourse)

Post 490576

(methyl_ethyl: "Peracetic Acid Titrative Assay", Newbee Forum)


MonoPerSuccinic Acid (PSA)

https://www.thevespiary.org/rhodium/Rhodium/pdf/baeyer-villiger.anisaldehyde.pdf



oxalic

Post 409755

(Ziqquratu: "Peroxalic Acid", Novel Discourse)


Alpha-halo Acids

Post 505628

(psyloxy: "CuCl/CuCl2/I2 a-iodination of propanoic acid - 90%", Chemistry Discourse)

Post 463377

(psyloxy: "alpha-bromopropanoic acid - a final word ?", Chemistry Discourse)


Acid Halides

Post 503173

(Rhodium: "Synthesis of Phenylacetyl Chloride", Methods Discourse)