The Vespiary

The Hive => Methods Discourse => Topic started by: cheeseboy on May 29, 2002, 08:41:00 AM

Title: acetone for methanol, swap. Less heat
Post by: cheeseboy on May 29, 2002, 08:41:00 AM

You think Acetone could be used instead of Methanol in the Oxone run? maybe the Acetone would keep the rxn running cooler to avoid kark happening. Anyone?

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May De Sorce Bee Wit Chu-Always
EDIT:
OOPs sorry, cheese now knows that Acetone reacts with Oxone to make a truly fine epoxidizing agent called...di...di..
anyone? Oh well, cheese will read harder before asking dumb questions again.
over and out

Title: Dioxirane
Post by: terbium on May 29, 2002, 04:19:00 PM

Search for dioxirane and you will get numerous relevant hits.

Post 220473 (https://www.thevespiary.org/talk/index.php?topic=6536.msg22047300#msg22047300)

(foxy2: "Re: Possible Peracetic Revision", Chemistry Discourse)

Post 220436 (https://www.thevespiary.org/talk/index.php?topic=6536.msg22043600#msg22043600)

(foxy2: "Re: Possible Peracetic Revision", Chemistry Discourse)

Post 220198 (https://www.thevespiary.org/talk/index.php?topic=6536.msg22019800#msg22019800)

(Rhodium: "Re: Possible Peracetic Revision", Chemistry Discourse)

Post 191173 (missing)

(Osmium: "Re: Potassium Monoperoxysulfate for spas~", Chemistry Discourse)

Post 189058 (https://www.thevespiary.org/talk/index.php?topic=12276.msg18905800#msg18905800)

(terbium: "Re: nitroethane", Novel Discourse)

Title: Dangerous
Post by: Sunlight on May 29, 2002, 06:53:00 PM

Dioxirane is defined as volatile organic peroxide, what means danger.

Title: Post deleted by cheeseboy
Post by: cheeseboy on May 29, 2002, 09:35:00 PM

Title: not really
Post by: goiterjoe on May 30, 2002, 02:05:00 AM

does oxone possess the potential to oxidize acetone  to acetone all the way to acetone peroxide, or does it always stop at dioxirane?

Title: acetone peroxide & oxone
Post by: Rhodium on June 04, 2002, 10:56:00 PM

I know that peroxymonosulfuric acid catalyzes the formation of dimeric and trimeric acetone peroxide, but I don't have any data on its potassium salt (= Oxone).