The Vespiary

The Hive => Chemistry Discourse => Topic started by: starlight on August 14, 2002, 03:55:00 PM

Title: reduction of dmmdp2np with urushibara?
Post by: starlight on August 14, 2002, 03:55:00 PM

Does anyone know whether is is possible to reduce dmmdp2np with urushibara, or does anyone have a view as to whether this is possible (tmp2np is possible where as it seems mdp2np is not).

many thanks.

./

Title: seems like it might not be
Post by: starlight on August 26, 2002, 02:47:00 PM

stumbled upon an answer to my own question, so thought I would post it for completeness:

"yes, the best yeilds 60%, were reported with P2NP, followed by TMP2NP at 55%, p-MP2NP at 25% and both MDP2NP and DMMDP2NP failed altogather with acidic activations. in most cases at least two rxns, in some like MDP2NP several times with a whole spectrum of variations."

can be found in a comment by Dr_Sister in the following document:

https://www.thevespiary.org/rhodium/Rhodium/chemistry/urushibara.txt (https://www.thevespiary.org/rhodium/Rhodium/chemistry/urushibara.txt)