Title: Re: Cleavage of oximes to C=O compounds w Mn(OAc)3
Post by: Osmium on October 04, 2001, 07:15:00 AM
What´s wrong with acid hydrolysis? Will the yields be lower?
Title: Re: Cleavage of oximes to C=O compounds w Mn(OAc)3
Post by: PEYOTE on October 04, 2001, 11:36:00 AM
No, it was another use of this chemical; havent you seen
Post 205055 (https://www.thevespiary.org/talk/index.php?topic=11741.msg20505500#msg20505500)
(Antoncho: "P2Ps from benzene, acetone and Mn(AcO)3", Novel Discourse)?
Title: Re: Cleavage of oximes to C=O compounds w Mn(OAc)3
Post by: Osmium on October 04, 2001, 01:02:00 PM
You confuse me.
Title: Re: Cleavage of oximes to C=O compounds w Mn(OAc)3
Post by: foxy2 on October 04, 2001, 10:29:00 PM
You can also epoxidize olefins with it. Do Your Part To Win The War
Title: Re: Cleavage of oximes to C=O compounds w Mn(OAc)3
Post by: PEYOTE on October 05, 2001, 02:35:00 AM
It can also be used for chlorination of alkenes (with acetic acid) -> Tetrahedron Lett. 26(6)(1984) 607 and as oxidant agent -> Wiad. Chem. (I dunno what journal it is) 30(10)(1976) 659.