The Vespiary

The Hive => Chemistry Discourse => Topic started by: Vitus_Verdegast on April 04, 2004, 03:51:00 PM

Title: Benzaldehyde chlorination w. SO2Cl2, does it work?
Post by: Vitus_Verdegast on April 04, 2004, 03:51:00 PM

Does anyone have any data on the possibility of chlorinating various substituted benzaldehydes with sulfuryl chloride?

TFSE only gave this

Post 465288 (missing)

(Rhodium: "Methoxybenzaldehyde Demethylation w/ MgI2*Et2O", Novel Discourse), where the following is briefly mentioned in the references section:

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(3) Compounds 2g and 3g were prepared by chlorination of corresponding salicylaldehydes with sulfuryl chloride, and these details will be reported soon in our synthetic study on mycochromenic acid.

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It would be interesting to have some data on the chlorination of 2,5-dimethoxybenzaldehyde.

Title: Sulfuryl chloride chlorination
Post by: Rhodium on April 04, 2004, 05:08:00 PM

There is also this forgotten gem:

Post 193730 (missing)

(foxy2: "Aromatic Chlorination of Interesting Amines", Chemistry Discourse)