Utility of silicon tetrafluoride as a catalyst of reactions with xenon difluoride: fluorinations of phenyl alkenes and benzaldehydes
Masanori Tamura*, Toshiyuki Takagi, Heng-dao Quan and Akira Sekiya National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
Received 29 March 1999; revised 10 May 1999; accepted 17 May 1999. Available online 22 May 2000.
AbstractApplication of silicon tetrafluoride to fluorinations with xenon difluoride as a catalyst is investigated. It was found that vic-difluorination of phenyl alkenes and transformation of benzaldehydes to difluoromethoxybenzenes using xenon difluoride are enhanced by silicon tetrafluoride.
Author Keywords: Silicon tetrafluoride; Xenon difluoride; Fluorination; Phenyl alkene; BenzaldehydesWould someone fetch the actual PDF as my account doesn't work for some reason
? DOI:
10.1016/S0022-1139(99)00103-7
Some editing done ... "I post these so seldom I didn't even notice the DOI function .."
"-Yeah, right"