The Vespiary

The Hive => Newbee Forum => Topic started by: landtrout on November 27, 2003, 12:18:00 AM

Title: safrole + performic = ???
Post by: landtrout on November 27, 2003, 12:18:00 AM

let us suppose that an isomerization failed and safrole was reacted with performic acid instead of iso-safrole, what would the product be? or would safrole come through unreacted?

thanks in advance

Title: I seems to remember the chief once described...
Post by: Bandil on November 27, 2003, 12:35:00 AM

I seem to remember the chief once described that scenario...

I think the conclusion was that you might get max 10% yield of MDP2P, where the main product would be "MDP3P"(or whatever it is called with the ketone-group at the end of the chain).

So isomerize correctly please  :)

Regards
Bandil

Title: if it is MDP3P it doesn't seem to want to form
Post by: landtrout on November 27, 2003, 03:26:00 AM

if it is MDP3P it doesn't seem to want to form a bisulfite adduct or the MP of the bisulfite adduct is very low

Title: The allyl isomer shows only low reactivity...
Post by: GC_MS on November 27, 2003, 01:16:00 PM

The allyl isomer shows only low reactivity towards peracids. UTFSE, it has been discussed 1.0E3 times before.

Title: safrole-iso-mdp2p
Post by: newbe_222 on November 28, 2003, 12:02:00 PM