Author Topic: safrole + performic = ???  (Read 2041 times)

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landtrout

  • Guest
safrole + performic = ???
« on: November 27, 2003, 12:18:00 AM »
let us suppose that an isomerization failed and safrole was reacted with performic acid instead of iso-safrole, what would the product be? or would safrole come through unreacted?

thanks in advance

Bandil

  • Guest
I seems to remember the chief once described...
« Reply #1 on: November 27, 2003, 12:35:00 AM »
I seem to remember the chief once described that scenario...

I think the conclusion was that you might get max 10% yield of MDP2P, where the main product would be "MDP3P"(or whatever it is called with the ketone-group at the end of the chain).

So isomerize correctly please  :)

Regards
Bandil


landtrout

  • Guest
if it is MDP3P it doesn't seem to want to form
« Reply #2 on: November 27, 2003, 03:26:00 AM »
if it is MDP3P it doesn't seem to want to form a bisulfite adduct or the MP of the bisulfite adduct is very low

GC_MS

  • Guest
The allyl isomer shows only low reactivity...
« Reply #3 on: November 27, 2003, 01:16:00 PM »
The allyl isomer shows only low reactivity towards peracids. UTFSE, it has been discussed 1.0E3 times before.


newbe_222

  • Guest
safrole-iso-mdp2p
« Reply #4 on: November 28, 2003, 12:02:00 PM »