The Vespiary

The Hive => Chemistry Discourse => Topic started by: Aurelius on February 24, 2004, 01:51:00 AM

Title: Compilation of Acid Reagents
Post by: Aurelius on February 24, 2004, 01:51:00 AM
Compilation of Acid Reagents

General Chemistry on Acid-Base theory

Post 204510 (missing)

(Rhodium: "Hofmann Acidity Scale (Funny)", General Discourse)

Post 445267 (missing)

(Aurelius: "Conjugate Acid-Bases and Their Relative Strengths", Chemistry Discourse)

Post 445288 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44528800#msg44528800)

(Aurelius: "Acid-Base Concepts", Chemistry Discourse)

Post 445301 (missing)

(Aurelius: "More acid-base concept chemistry", Chemistry Discourse)

Post 445317 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44531700#msg44531700)

(Aurelius: "Relative Strengths of Acids and Bases", Chemistry Discourse)

Post 445416 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44541600#msg44541600)

(Aurelius: "Acid-Base Charts", Chemistry Discourse)

Post 445436 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44543600#msg44543600)

(Aurelius: "Amphiprotism", Chemistry Discourse)

Post 445485 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44548500#msg44548500)

(Aurelius: "The Leveling Effect", Chemistry Discourse)

Post 445654 (missing)

(Aurelius: "Neutralization Reactions", Chemistry Discourse)

Post 445659 (missing)

(Aurelius: "Preparing Weak Acids from Salts and Strong Acids", Chemistry Discourse)

Post 445667 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44566700#msg44566700)

(Aurelius: "Hydrolysis Reactions", Chemistry Discourse)

Post 445692 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44569200#msg44569200)

(Aurelius: "Hydrolysis of Salts, Indicators and Buffers", Chemistry Discourse)

Post 445735 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44573500#msg44573500)

(Aurelius: "Structure and Its Effect Upon Acidity and Basicity", Chemistry Discourse)

Post 445752 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44575200#msg44575200)

(Aurelius: "Electronegativity, Acidity, Basicity and Trends", Chemistry Discourse)

Post 445868 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44586800#msg44586800)

(Aurelius: "The Hydrogen Halide Problem", Chemistry Discourse)

Post 445880 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44588000#msg44588000)

(Aurelius: "Acidity, Basicity and Ion Size", Chemistry Discourse)

Post 445933 (https://www.thevespiary.org/talk/index.php?topic=7711.msg44593300#msg44593300)

(Aurelius: "Lewis Concept of Acidity and Basicity", Chemistry Discourse)


Physical data for all acids listed below can be found here.

Post 445906 (missing)

(Aurelius: "Acid Reagents Physical Properties", Chemistry Discourse)


Pka's of acids in water

http://www.stanford.edu/~travisw/pkas.pdf (http://www.stanford.edu/~travisw/pkas.pdf)



Common Buffer Systems

http://ptcl.chem.ox.ac.uk/MSDS/buffers.html (http://ptcl.chem.ox.ac.uk/MSDS/buffers.html)



General Methods for the synthesis of carboxylic acids:

Post 446181 (https://www.thevespiary.org/talk/index.php?topic=6912.msg44618100#msg44618100)

(ChemisTris: "Mathews’ rxn(MW): carboxylic acids from nitriles", Chemistry Discourse)


HCl acid

Post 76013 (https://www.thevespiary.org/talk/index.php?topic=11707.msg7601300#msg7601300)

(PolytheneSam: "Re: bromosafrole", Novel Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/hclgas.argox.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/hclgas.argox.html)


https://www.thevespiary.org/rhodium/Rhodium/chemistry/hcl-gas.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/hcl-gas.html)



HI acid

Post 288929 (missing)

(Rhodium: "Hydriodic Acid From Pinene and Iodine", Stimulants)

Post 271993 (https://www.thevespiary.org/talk/index.php?topic=8645.msg27199300#msg27199300)

(Argox: "Hydriodic Acid--Step by Step Write-Up", Stimulants)

see also: 

https://www.thevespiary.org/rhodium/Rhodium/chemistry/hydriodic.argox.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/hydriodic.argox.html)


Post 318864 (https://www.thevespiary.org/talk/index.php?topic=11269.msg31886400#msg31886400)

(3base: "aq.HBr/HI from KBr/KI & tartaric acid", Novel Discourse)

Post 216544 (missing)

(Stonium: "Re: Shelf life of Hydroidic Acid ?", Newbee Forum)

Post 381437 (https://www.thevespiary.org/talk/index.php?topic=7049.msg38143700#msg38143700)

(Rhodium: "Electrolytic HI", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/hydriodic.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/hydriodic.html)


Post 398185 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39818500#msg39818500)

(Aurelius: "HI acid via tetralin/decalin", Methods Discourse)

Post 398187 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39818700#msg39818700)

(Aurelius: "HI acid via ascorbic acid and iodine", Methods Discourse)

Post 398198 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39819800#msg39819800)

(Aurelius: "Preparation of Pure Anhydrous HI in GAA", Methods Discourse)


HBr acid

Post 318864 (https://www.thevespiary.org/talk/index.php?topic=11269.msg31886400#msg31886400)

(3base: "aq.HBr/HI from KBr/KI & tartaric acid", Novel Discourse)

Post 76013 (https://www.thevespiary.org/talk/index.php?topic=11707.msg7601300#msg7601300)

(PolytheneSam: "Re: bromosafrole", Novel Discourse)

Post 381399 (https://www.thevespiary.org/talk/index.php?topic=7049.msg38139900#msg38139900)

(PolytheneSam: "Electrolytic HBr", Chemistry Discourse)

Post 191676 (missing)

(abc123: "HBr gas?", Chemistry Discourse)


HF acid

HNO3

Post 76013 (https://www.thevespiary.org/talk/index.php?topic=11707.msg7601300#msg7601300)

(PolytheneSam: "Re: bromosafrole", Novel Discourse)

Post 398201 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39820100#msg39820100)

(Aurelius: "100% Nitric Acid", Methods Discourse)

Post 398202 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39820200#msg39820200)

(Aurelius: "Preparation of Nitric Acid", Methods Discourse)

Post 398207 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39820700#msg39820700)

(Aurelius: "Preparation of Anhydrous Nitric acid in DCM", Methods Discourse)


H2S acid

Post 328633 (missing)

(lugh: "H2S", General Discourse)


HCN

Acetic Acid

Acetic Anhydride

Post 506730 (https://www.thevespiary.org/talk/index.php?topic=6427.msg50673000#msg50673000)

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)

Post 462958 (https://www.thevespiary.org/talk/index.php?topic=11772.msg46295800#msg46295800)

(Rhodium: "Na-Acetate + Na-Pyrosulfate -> Acetic Anhydride", Novel Discourse)

Post 247630 (missing)

(terbium: "Re: Acetic Anhydride", Chemicals & Equipment)

Post 216197 (https://www.thevespiary.org/talk/index.php?topic=6597.msg21619700#msg21619700)

(Antoncho: "A completely OTC ;) acetic anhydride synthesis", Chemistry Discourse)

Post 391980 (https://www.thevespiary.org/talk/index.php?topic=11884.msg39198000#msg39198000)

(BillyBoy: "From Ketene", Novel Discourse)

Post 391938 (https://www.thevespiary.org/talk/index.php?topic=11884.msg39193800#msg39193800)

(Mountain_Girl: "AA from Acetaldehyde", Novel Discourse)

Post 274280 (https://www.thevespiary.org/talk/index.php?topic=9102.msg27428000#msg27428000)

(foxy2: "Re: first encouraging ketenelamp experiment", Methods Discourse)

Post 98307 (missing)

(Stik E. Fingers: "Acetic anhydride from acetic acid and a salt", Chemistry Discourse)

Post 162355 (missing)

(drone 342: "Acetic Anhydride---again", Chemicals & Equipment)

http://www.orgsyn.org/orgsyn/prep.asp?prep=cv1p0330 (http://www.orgsyn.org/orgsyn/prep.asp?prep=cv1p0330)


https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html)


Post 171900 (missing)

(Cheapskate: "Acetic Anhydride---again", Chemicals & Equipment)

Post 470665 (https://www.thevespiary.org/talk/index.php?topic=7097.msg47066500#msg47066500)

(psyloxy: "acetic / propionic anhydride from NaO(Me)Ac + TsCl", Chemistry Discourse)



Acetyl Chloride

Post 506730 (https://www.thevespiary.org/talk/index.php?topic=6427.msg50673000#msg50673000)

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html)



Carbonic Acid

ChloroAcetic Acid

https://www.thevespiary.org/rhodium/Rhodium/chemistry/chloroacetic.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/chloroacetic.html)



Chlorosulfonic Acid

Post 311279 (missing)

(foxy2: "chlorosulfonic acid", Chemistry Discourse)


Acetone Dicarboxylic Acid

http://www.orgsyn.org/orgsyn/orgsyn/prepcontent.asp?print=1&showprint=1&prep=cv1p0010 (http://www.orgsyn.org/orgsyn/orgsyn/prepcontent.asp?print=1&showprint=1&prep=cv1p0010)



Anthranilic acid

Post 413466 (https://www.thevespiary.org/talk/index.php?topic=11285.msg41346600#msg41346600)

(pHarmacist: "Two Methods for the Preparation of Phthalimide", Novel Discourse)

Post 108807 (https://www.thevespiary.org/talk/index.php?topic=11496.msg10880700#msg10880700)

(dormouse: "Anthranilic acid from phthalimide using OTC sodiumhypochlorite solution  -Methaco(s)m", Novel Discourse)

Post 108859 (missing)

(dormouse: "Anthranlic acid a la Cheapskate  -Cheapskate", Novel Discourse)


Cinnamic Acid

Post 501647 (https://www.thevespiary.org/talk/index.php?topic=12235.msg50164700#msg50164700)

(Rhodium: "Cinnamic Acids from Malonic acid/Benzaldehyde", Novel Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/cinnamic.txt (https://www.thevespiary.org/rhodium/Rhodium/chemistry/cinnamic.txt)



Citric acid

https://www.thevespiary.org/rhodium/Rhodium/chemistry/citricacid.txt (https://www.thevespiary.org/rhodium/Rhodium/chemistry/citricacid.txt)



MeO substituted Acids

3,4-Dimethoxyphenylpyruvic Acid

Post 413165 (https://www.thevespiary.org/talk/index.php?topic=9644.msg41316500#msg41316500)

(Rhodium: "Old MDPEA synthesis", Methods Discourse)
 
3,4-Dimethoxyphenylacetic Acid

Post 413165 (https://www.thevespiary.org/talk/index.php?topic=9644.msg41316500#msg41316500)

(Rhodium: "Old MDPEA synthesis", Methods Discourse)
 
3,4-Methylenedioxycinnamic Acid

Post 413165 (https://www.thevespiary.org/talk/index.php?topic=9644.msg41316500#msg41316500)

(Rhodium: "Old MDPEA synthesis", Methods Discourse)


Diphenylacetic acid

https://www.thevespiary.org/rhodium/Rhodium/pdf/substituted.diphenylacetic.pdf (https://www.thevespiary.org/rhodium/Rhodium/pdf/substituted.diphenylacetic.pdf)


Post 398785 (missing)

(Aurelius: "Preparation of Diphenylacetic acid", General Discourse)


Formic acid

Post 449230 (https://www.thevespiary.org/talk/index.php?topic=6008.msg44923000#msg44923000)

(abolt: "Formic acid S.G.", Chemicals & Equipment)

Post 216070 (https://www.thevespiary.org/talk/index.php?topic=7035.msg21607000#msg21607000)

(foxy2: "Make Formic Acid and Hydroxylamine in one step!!", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/formic.acid.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/formic.acid.html)


Post 468940 (https://www.thevespiary.org/talk/index.php?topic=12176.msg46894000#msg46894000)

(ning: "Oxalic and formic acid  from sawdust", Novel Discourse)


Hydrogen Carbonate Salts(acidic) HCO3-

Hypophosphorus acid (H2PO2)

Post 246126 (missing)

(lugh: "Hypophosphoric Acid Synthesis", Chemicals & Equipment)


Lysergic Acids and Related Acids

Post 403852 (https://www.thevespiary.org/talk/index.php?topic=13323.msg40385200#msg40385200)

(pHarmacist: "Synthesis of Lysergic Acid Derivatives", Tryptamine Chemistry)


Mandelic acid

Post 479855 (https://www.thevespiary.org/talk/index.php?topic=6924.msg47985500#msg47985500)

(dioulasso: "Substituted Mandelic acids", Chemistry Discourse)

Post 504013 (https://www.thevespiary.org/talk/index.php?topic=7516.msg50401300#msg50401300)

(starlight: "some interesting mandelic acid patents", Chemistry Discourse)

Post 248176 (missing)

(timsong: "Mandelic Acid Synth", Stimulants)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/mandelic.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/mandelic.html)


Post 400338 (missing)

(Rhodium: "Resolution of dl-Ephedrine", Stimulants)


Nitrous Acid

Oxalic Acid

https://www.thevespiary.org/rhodium/Rhodium/chemistry/formic.acid.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/formic.acid.html)


http://www.geocities.com/Baja/Canyon/2609/cleaners.html (http://www.geocities.com/Baja/Canyon/2609/cleaners.html)


Post 468940 (https://www.thevespiary.org/talk/index.php?topic=12176.msg46894000#msg46894000)

(ning: "Oxalic and formic acid  from sawdust", Novel Discourse)

Post 473728 (https://www.thevespiary.org/talk/index.php?topic=5443.msg47372800#msg47372800)

(ning: "Improved Oxalic Acid Extraction", Chemicals & Equipment)


Oxalyl chloride (oxalic chloride)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/oxalylchloride.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/oxalylchloride.html)



Para-Toluene Sulfonic Acid (p-Tosic acid)
 

Post 505622 (https://www.thevespiary.org/talk/index.php?topic=6576.msg50562200#msg50562200)

(psyloxy: "H2SO4 + toluene --> p-tosic acid", Chemistry Discourse)

Post 288713 (https://www.thevespiary.org/talk/index.php?topic=9044.msg28871300#msg28871300)

(Chromic: "Getting higher yields with p-tosic acid", Methods Discourse)

Post 389646 (https://www.thevespiary.org/talk/index.php?topic=9366.msg38964600#msg38964600)

(Antoncho: "Toluenesulfonic acid - tips and tricks.", Methods Discourse)

Post 261000 (https://www.thevespiary.org/talk/index.php?topic=6776.msg26100000#msg26100000)

(Chromic: "p-toluenesulfonic acid", Chemistry Discourse)

Post 261199 (https://www.thevespiary.org/talk/index.php?topic=6776.msg26119900#msg26119900)

(terbium: "Re: p-toluenesulfonic acid", Chemistry Discourse)

Post 273447 (https://www.thevespiary.org/talk/index.php?topic=6776.msg27344700#msg27344700)

(Rhodium: "Re: p-toluenesulfonic acid", Chemistry Discourse)

Post 389646 (https://www.thevespiary.org/talk/index.php?topic=9366.msg38964600#msg38964600)

(Antoncho: "Toluenesulfonic acid - tips and tricks.", Methods Discourse)


Perchloric Acid

Phenyl Acetic Acid

From Cinnamic Acid:

Post 509760 (https://www.thevespiary.org/talk/index.php?topic=7672.msg50976000#msg50976000)

(Rhodium: "Cinnamaldehyde -Oxone-> Phenylacetic Acid", Chemistry Discourse)
(40% yields w/oxone in aq. acetone!)

Post 413520 (https://www.thevespiary.org/talk/index.php?topic=11886.msg41352000#msg41352000)

(Aurelius: "phenylacetic acid", Novel Discourse)

phenyl acetic acid patents

Post 370541 (https://www.thevespiary.org/talk/index.php?topic=12177.msg37054100#msg37054100)

(Lilienthal: "We have a patent markup...", Novel Discourse)

phenylacetic acid from ethylbenzene

Post 219903 (missing)

(Bwiti: "Phenylacetic Acid from Ethylbenzene", Methods Discourse)

Post 219657 (missing)

(obituary: "Re: ethylbenzene", General Discourse)

?

Post 203572 (https://www.thevespiary.org/talk/index.php?topic=11832.msg20357200#msg20357200)

(obituary: "phenylacetic acid", Novel Discourse)

Post 413520 (https://www.thevespiary.org/talk/index.php?topic=11886.msg41352000#msg41352000)

(Aurelius: "phenylacetic acid", Novel Discourse)

Post 108296 (https://www.thevespiary.org/talk/index.php?topic=11303.msg10829600#msg10829600)

(dormouse: "phenylacetic acid  -Scooby Doo", Novel Discourse)

Post 412602 (missing)

(Aurelius: "PhenylAcetic Acid", Stimulants)


Phenylglyoxylic Acid

Post 500342 (https://www.thevespiary.org/talk/index.php?topic=7196.msg50034200#msg50034200)

(Rhodium: "Phenylglyoxylic Acid from Styrene", Chemistry Discourse)


PolyPhosphoric Acid

Post 398338 (https://www.thevespiary.org/talk/index.php?topic=9688.msg39833800#msg39833800)

(Aurelius: "repost", Methods Discourse)


Propionic Acid

Post 449395 (https://www.thevespiary.org/talk/index.php?topic=7305.msg44939500#msg44939500)

(Aurelius: "Propionic acid", Chemistry Discourse)

Post 463633 (https://www.thevespiary.org/talk/index.php?topic=6375.msg46363300#msg46363300)

(psyloxy: "propionic acid from n-propanol / HNO3 - 84% yield", Chemistry Discourse)

Post 461624 (https://www.thevespiary.org/talk/index.php?topic=11660.msg46162400#msg46162400)

(Antoncho: "Propionic acid from MEK - let's find it out!", Novel Discourse)

Post 461856 (https://www.thevespiary.org/talk/index.php?topic=11660.msg46185600#msg46185600)

(roger2003: "Old Ways - Mabe, they are helpful", Novel Discourse)

Post 463793 (https://www.thevespiary.org/talk/index.php?topic=11660.msg46379300#msg46379300)

(Rhodium: "Propionic Acid from Methyl Ethyl Ketone/Ca(OCl)2", Novel Discourse)

Post 463795 (https://www.thevespiary.org/talk/index.php?topic=11660.msg46379500#msg46379500)

(roger2003: "Propionic Acid from Propanol", Novel Discourse)

Post 463783 (https://www.thevespiary.org/talk/index.php?topic=11660.msg46378300#msg46378300)

(roger2003: "Propionic acid from MEK", Novel Discourse)


Propionic Anhydride

Post 506730 (https://www.thevespiary.org/talk/index.php?topic=6427.msg50673000#msg50673000)

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)

Post 470665 (https://www.thevespiary.org/talk/index.php?topic=7097.msg47066500#msg47066500)

(psyloxy: "acetic / propionic anhydride from NaO(Me)Ac + TsCl", Chemistry Discourse)

https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html (https://www.thevespiary.org/rhodium/Rhodium/chemistry/anhydrides.html)



Propionyl Chloride

Post 506730 (https://www.thevespiary.org/talk/index.php?topic=6427.msg50673000#msg50673000)

(psyloxy: "SiCl4 / Ph(COCl)x way to acid chlorides + anhyd.", Chemistry Discourse)


Pyruvic Acid

Post 463560 (https://www.thevespiary.org/talk/index.php?topic=12453.msg46356000#msg46356000)

(roger2003: "Pyruvic Acid", Serious Chemistry)

Post 384565 (missing)

(cthulhujr: "Pyruvic Acid Synthesis and 24%", Stimulants)


Sulfuric Acid

Sulfurous Acid

Per- Acids

In General:

Post 415088 (https://www.thevespiary.org/talk/index.php?topic=6488.msg41508800#msg41508800)

(GC_MS: "The synthesis of peracids", Chemistry Discourse)


m-Chloroperbenzoic acid

https://www.thevespiary.org/rhodium/Rhodium/pdf/mcpba.pdf (https://www.thevespiary.org/rhodium/Rhodium/pdf/mcpba.pdf)


https://www.thevespiary.org/rhodium/Rhodium/pdf/m-cpba.pdf (https://www.thevespiary.org/rhodium/Rhodium/pdf/m-cpba.pdf)




acetic

Post 413717 (https://www.thevespiary.org/talk/index.php?topic=6748.msg41371700#msg41371700)

(GC_MS: "Determination of peracid content", Chemistry Discourse)

Post 490576 (https://www.thevespiary.org/talk/index.php?topic=10891.msg49057600#msg49057600)

(methyl_ethyl: "Peracetic Acid Titrative Assay", Newbee Forum)


MonoPerSuccinic Acid (PSA)

https://www.thevespiary.org/rhodium/Rhodium/pdf/baeyer-villiger.anisaldehyde.pdf (https://www.thevespiary.org/rhodium/Rhodium/pdf/baeyer-villiger.anisaldehyde.pdf)



oxalic

Post 409755 (https://www.thevespiary.org/talk/index.php?topic=12239.msg40975500#msg40975500)

(Ziqquratu: "Peroxalic Acid", Novel Discourse)


Alpha-halo Acids

Post 505628 (https://www.thevespiary.org/talk/index.php?topic=7042.msg50562800#msg50562800)

(psyloxy: "CuCl/CuCl2/I2 a-iodination of propanoic acid - 90%", Chemistry Discourse)

Post 463377 (https://www.thevespiary.org/talk/index.php?topic=6375.msg46337700#msg46337700)

(psyloxy: "alpha-bromopropanoic acid - a final word ?", Chemistry Discourse)


Acid Halides

Post 503173 (https://www.thevespiary.org/talk/index.php?topic=8901.msg50317300#msg50317300)

(Rhodium: "Synthesis of Phenylacetyl Chloride", Methods Discourse)