Author Topic: Oxydation of alkenes catalysed with silver  (Read 2981 times)

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claude

  • Guest
Oxydation of alkenes catalysed with silver
« on: September 01, 2004, 12:04:00 PM »
I know that industrially, glycol (1,2-ethandiol) OH-CH2-CH2-OH is produced by oxydation of ethylene by atmospheric O2, in presence of silver as catalyst. But it seems that this reaction is only used with one alkene : ethylene. Do you know if this reaction can be applied to other alkenes, or why it can't ?

Rhodium

  • Guest
Aerobic Alkene Oxidation
« Reply #1 on: September 01, 2004, 05:29:00 PM »
But it seems that this reaction is only used with one alkene : ethylene. Do you know if this reaction can be applied to other alkenes, or why it can't?

For a similar reaction catalyzed by DMSO instead of silver, check out

Post 451720

(Rhodium: "Isosafrole to MDP2P by auto-oxidation!", Novel Discourse)


The O2 Wacker Oxidation is also similar, in that it uses a noble metal catalyst to oxidize alkenes with oxygen:

https://www.thevespiary.org/rhodium/Rhodium/chemistry/dmfo2wacker.html


https://www.thevespiary.org/rhodium/Rhodium/chemistry/wacker.krv.html