ware & geez, all that information and discussion on my questions was and is much appreciated
I don't think it has to be too strainful catching up with responses, but now isn't the time unfortunetly, but I wanted to say that it was very nice of you to go to all that trouble.
The orange gak is nasty
The dry-mixing of the base is a side-step, a work-around.
But it's limited
See, the task is to provide for the pfed an alternative
What would be ideal, to make the dry-basing a full yielding side-step is to cause a change of polarity with no water present. Just a Non-polar for the newly formed pfed freebase. Bubbles? moist air? some so of mechanical reflux or mixing at some special stage which. talk bout later, very tired.
At this point, the orange gak can be removed with strong basic water washes, safely and quantitatively. See?
I'm not sure that this oil is slightly soluble in non-polar as you theorize...I was leaning more towards the orange formed upon over-basification providing a solvent for transiting a second compound?
But you probably have a better idea because I get the strong impression that you have been described things on a bigger scale where things are more clear.
The haughty chloroform gloater, SPISSHAK, might bee having success removing it in a procedure with no polarity change because the orange isnt dissolved by the chloroform?
Using a liquid-liquid exaction of the over-based orange water would bee spectacular.
But theres uncertainties when you consider this orange, strongly water soluble non-volitile, which
If you concentrate it, it's more dense...ohh it looks like a lot of water is the key to free the free base, as hellman and bos have said.
I want to know if this orange stuff is less efficient at dissolving pfed.fb in hot or cold conditions, as this will allow for a minimum amount of water.
oh (very tired). but as the pfed is released in to the NP, there will be fresh room in it to dissolve more pfed.fb in a given amount of water. dunno
Ware what would bee a pleasurable outcome is a proper liquid-liquid extraction, or to crash out/salt out.
DCM washed out PEG like she's a girl, well she is a girl.
ohh that could help for the basing with little to no water present, as it provides a bottom-layer and a top layer of non-polar for the pfed.fb escapees.
a tetra wash would bee essential in agreiches procedure.
ohh a solvent above and below the basing process would double the escape routes, thus leaving less opportunity to dissolve in this orange.
shaking in this environment might help crack this fun puzzle too? i got no idea, bed.
i know what about the washing machine?