In Post 36700 (https://www.thevespiary.org/talk/index.php?topic=7588.msg3670000#msg3670000)
(CHEM_GUY: "Re: benzyl chloride from hypochlorite salts", Chemistry Discourse); a procedure is given for separating such an azeotrope.
The excess toluene is distilled, and then three pints of 99% isopropyl alcohol is added (at least 1230ml), to deal with the toluene/benzyl chloride azeotrope. The toluene/isopropanol azeotrope distills at 80.6 degrees centrigrade, and then the excess isopropanol distills at 82.4 degrees centrigrade.
Since the exact composition of your mixture is unknown, one should probably use quite a bit of isopropyl alcohol :)