Author Topic: bps and mps of various propenyl and allylbenzenes  (Read 2863 times)

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hypo

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bps and mps of various propenyl and allylbenzenes
« on: June 17, 2002, 10:39:00 PM »
i looked up in beilstein the boilingpoints and meltingpoints of
interesting propenyl- and allyl-benzenes. this may be of interest
to others too...


Apiole
mp in °C (solvent):
   29.5
   30
   30
   27.5
   28.5-29 (pet. ether)
bp in °C (pressure in torr):
   294
   179 (34)

Propenylbenzene of apiole
mp in °C (solvent):
   56.5 (aq. ethanol)
   56
   55-56
   46

Myristicin
mp in °C (solvent):
   -30
bp in °C (pressure in torr):
   91 (0.4)
   94-95 (0.4)
   95-97 (0.02)
   115-116
   198
   276-277
   173 (40)
   148-150 (15)
   149-149.6 (15)
   149.5 (15)

Propenylbenzene of myristicin (rac)
mp in °C (solvent):
   44
   44
   44-45
   42.5 (aq. methanol)
bp in °C (pressure in torr):
   166 (18)

Propenylbenzene of myristicin (trans)
mp in °C (solvent):
   44
   42-44
   42-44
   38
bp in °C (pressure in torr):
   166 (18)

Dillapiole
bp in °C (pressure in torr):
   285
   294-295
   283 (764)
   165-168 (20)
   172-173 (16)
   157-158 (13)
   162 (11)

iso-Dillapiole (trans)
mp in °C (solvent):
   44 (hexane)

iso-Dillapiole (rac)
mp in °C (solvent):
   44 (light petroleum)
   44
bp in °C (pressure in torr):
   296

Safrole
mp in °C (solvent):
   11.2
   11
   11 (pet. ether)
   11
bp in °C (pressure in torr):
   62-63 (0.2)
   231-233
   232-233
   234.5 (760)
   234.5 (760)
   235.9 (760)
   162.2 (100)
   114-115 (15)
   104 (11)
   106.4 (10)
   104-105 (6)
   93-93.2 (5)
   94-94.5 (4)
   140 (4)
   145 (4.5)
   69-70 (1.5)
   90 (2)

iso-Safrole (cis)
mp in °C (solvent):
   -21.5
bp in °C (pressure in torr):
   77-79 (3.5)

iso-Safrole (trans)
mp in °C (solvent):
   8.2
   6.6-6.7 (pet. ether)
bp in °C (pressure in torr):
   85-86 (3.4)

Anethole (trans)
mp in °C (solvent)
   21.35
   22
   22-22.5
bp in °C (pressure in torr):
   64 (0.5)
   233-234
   234-234.5 (763)
   119-120 (18)
   115.5-116.5 (16)
   108 (12)
   115 (12)
   94-95 (4.5)
   66.7 (2)
   79.5-80.5 (2)
   81-81.5 (2.3)
   81-81.5 (2.3)

Anethole (rac)
mp in °C (solvent):
   21.65
   22.5
   22.3
   21.3
   21.5
   22.5-23
   22.3-22.5
   20.5-21.5
   21-22
bp in °C (pressure in torr):
   63-64 (0.2)
   231-233
   235.2 (760)
   235.3 (760)
   233-233.5 (751.1)
   233-234 (751)
   233.6 (731)
   231.7 (700)
   122-124 (23)
   100-112 (15.000001)
   112-114 (15)
   113.5 (14)
   104 (12)
   88-90 (5)
   79.5-80.5 (2)

2,3,4,5-Tetramethoxy-1-allylbenzene
mp in °C (solvent):
   25 (ethanol)
   25
   25
bp in °C (pressure in torr):
   145 (12)

Elemicin
bp in °C (pressure in torr):
   152-156 (17)
   144-147 (10)
   144-147 (10)
   148-149 (10)
   106-107 (1)

Propenylbenzene of elemicin (trans)
mp in °C (solvent):
   17-18
   17-18 (hexane)
bp in °C (pressure in torr):
   110-115 (0.4)

Propenylbenzene of elemicin (rac)
bp in °C (pressure in torr):
   153-156 (10)
   153-156 (10)
   152-153 (9)
   152-154 (9)
   145-147 (6)
   142-148 (3)