Author Topic: reduction of dmmdp2np with urushibara?  (Read 1286 times)

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starlight

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reduction of dmmdp2np with urushibara?
« on: August 14, 2002, 03:55:00 PM »
Does anyone know whether is is possible to reduce dmmdp2np with urushibara, or does anyone have a view as to whether this is possible (tmp2np is possible where as it seems mdp2np is not).

many thanks.

./

starlight

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seems like it might not be
« Reply #1 on: August 26, 2002, 02:47:00 PM »
stumbled upon an answer to my own question, so thought I would post it for completeness:

"yes, the best yeilds 60%, were reported with P2NP, followed by TMP2NP at 55%, p-MP2NP at 25% and both MDP2NP and DMMDP2NP failed altogather with acidic activations. in most cases at least two rxns, in some like MDP2NP several times with a whole spectrum of variations."

can be found in a comment by Dr_Sister in the following document:

https://www.thevespiary.org/rhodium/Rhodium/chemistry/urushibara.txt