Might well come under the category of "funky", but what about creating cyclohexyl, or pinacolyl substituted amphetamines?
Having said that, I have yet to see a psycoactive substance with a pinacolyl substitution, going off on a tangent a little, but maybe it would produce an interesting PCP analogue, PPP maybe, or some interesting new tryptamines/phens
The alcohol is available I think, from some farming products, a sheep dip type of thing as I remember, although it would bee quite hard to obtain, due to its more unsavoury uses, beeing one of the precursors to the nerve agent soman.