Bromination of ketones can be carried out in a wide range of solvents; glacial acetic acid is often a solvent of choice, as is DCM. Chloroform, carbon tetrachloride, ethers, alcohols and alkanes (e.g. hexane) can all be used, and I'd only really recommend against using
acetone...
The above solvents all work with varying degrees of success depending on the substrate. When brominating propiophenones, DCM is my favourite solvent, as the reaction is over in minutes in almost quantitative yield, and the workup is simple.
If I were you I'd try it in DCM. You may even be able to add the methylamine in the next step without removing the solvent and replacing it with benzene. DCM is a good solvent for the SN
2 swap with methylamine for the bromine of alpha-bromoketones.
1There is an appreciable difference between the bromination of propiophenones (which my advice is based upon) and that of (O-chlorophenyl)-cyclopentylketone, which is the substrate you're looking to brominate. There may be something which makes DCM unsuitable (solubility, or greatly differing reactivity in different solvents), but it's probably the best bet if you don't want to use CCl
4.
1 For example, see the second step of
Post 475219
(Kinetic: "Benzene -> methaephetamine", Novel Discourse)Also related:
Post 479479 (missing)
(Kinetic: "Solvent", Newbee Forum)