The Vespiary

The Hive => Newbee Forum => Topic started by: neohippy on July 26, 2003, 03:03:00 AM

Title: Esters to Amides
Post by: neohippy on July 26, 2003, 03:03:00 AM

http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=CV6P0492 (http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=CV6P0492)

Uses trimethylaluminum(not good with oxygen).

http://www.mdpi.net/ecsoc-5/e0013/e0013.htm (http://www.mdpi.net/ecsoc-5/e0013/e0013.htm)

Uses the microwave.

Title: Microwave
Post by: Aurelius on July 26, 2003, 03:43:00 PM

The microwave reference is great!  The first one is just a little hard to work using light weight amines (freebase methylamine).

Title: I wonder
Post by: neohippy on July 26, 2003, 06:15:00 PM

If this method could work with lysergic molecules?
Low wattage for a couple minutes. Found one reference on rhodiums site that may shed some light on this:

"Effect of autoclaving and conventional and microwave baking on the
ergot alkaloid and chlorogenic acid contents of morning glory (Ipomoea
tricolor Cav. cv.) heavenly blue seeds.

Friedman, M.; Dao, L. (1990)  J Agr Food Chem 38(3):805-808"