Electrolytic reductions.
Ok I know alot of people participated in the contest and surely somebody has copies of the procedures on hand???
WEll if anybody has access to any of the reduction methods listed below that have references to electrolytic reduction please post them when it is convient for you if it isn't too much trouble to get them and post them. You can omit some of the standard chemical process to save room or time as I'm only interested in the electrochemical methods.
Reaction Classification Preparation
Reagent ethanol
acetic acid
aqueous sulfuric acid
Other conditions Electrolysis.an einer Quecksilber-Kathode
Ref. 1 2252728; Journal; Alles; JACSAT; J.Amer.Chem.Soc.; 54; 1932; 271,273;
Reaction Classification Preparation
Reagent ethanol
acetic acid
aqueous hydrochloric acid
Other conditions Electrolysis
Ref. 1 532257; Journal; Bruckner; JLACBF; Justus Liebigs Ann. Chem.; 518; 1935; 226, 242;
Reaction Classification Preparation
Reagent lead-cathode
acetic acid
aqueous hydrochloric acid
Other conditions Electrolysis
Ref. 1 532130; Journal; Kondo; Kataoka; ITKNA6; Itsuu Kenkyusho Nempo; 2; 1951; 7, 10; engl. Ref. S. 43, 48; Chem.Abstr.; 1953; 7519;
Reaction Classification Preparation
Reagent lead-cathode
ethanol
acetic acid
Other conditions Electrolysis.Reagens 4: wss. Salzsaeure
Ref. 1 532128; Journal; Schultz; Arnold; JACSAT; J.Amer.Chem.Soc.; 71; 1949; 1911, 1913;
Ref. 2 532129; Journal; Slotta; Haberland; ANCEAD; Angew.Chem.; 46; 1933; 766, 769;
Reaction Classification Chemical behaviour
Other conditions Electrolysis
Ref. 1 1705573; Journal; Kondo; Ishiwata; CHBEAM; Chem.Ber.; 64; 1931; 1533, 1636;
Reaction Classification Preparation
Other conditions Electrolysis
Ref. 1 532307; Journal; Sugasawa; Hino; PHBUA9; Pharm.Bull.; 2; 1954; 242, 245
Reaction Classification Preparation
Reagent 0.3 M H2SO4
Solvent propan-2-ol
H2O
Yield 60. (BRN507867)
Temperature 10 - 15 øC
Other conditions electrolysis
Ref. 1 5601939; Journal; Wessling, Michael; Schaefer, Hans J.; CHBEAM; Chem.Ber.; EN; 124; 10; 1991; 2303-2306;
Reaction Classification Preparation
Reagent 1 N H2SO4
Solvent acetonitrile
H2O
Other conditions electrolysis; pH1.16
Ref. 1 5663729; Journal; Marcot, Bernard; Rabaron, Alain; Viel, Claude; Bellec, Christian; Deswarte, Stephane; Maitte, Pierre; CJCHAG; Can.J.Chem.; FR; 59; 1981; 1224-1234
Reaction Classification Preparation
Other conditions (electrochemical reduction)
Ref. 1 16508; Journal; Bessho,K.; CPBTAL; Chem.Pharm.Bull.; EN; 11; 1963; 1500-1503
Reaction Classification Preparation
Reagent aq. HCl, AcOH
Solvent tetrahydrofuran
methanol
Other conditions (electrochemical reduction)
Ref. 1 16506; Journal; Bessho,K.; CPBTAL; Chem.Pharm.Bull.; EN; 11; 1963; 1491-1494;