I need help in finding out how to make DMT-MM. DMT-MM is a dehydrating condensing agent. DMT-MM can be prepared at low cost from iexpensive cyanuric chloride, but I don't know how.....java
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Post 513353
(java: "Reduction of Carboxylic Acids to Aldehydes.....", Novel Discourse) Post 513869
(java: "Onepot condensation of carboxylic acids and amines", Novel Discourse)Cyanuric chloride reading.
Post 383427
(Rhodium: "Triazine-Promoted Amidation of Carboxylic Acids", Novel Discourse)Edited by java 6-17-04Ref. needed..
Synthesis and characterization
of 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-
4-methylmorpholinium chloride.(DMT-MM) TetrahedronLett. 40, 5327–5330.1999DOI:
:10.1016/S0040-4039(99)00968-5
Kunishima, M., Kawachi, C., Iwasaki, F., Terao, K.
& Tani, S. (1999)
Abstract4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride (DMTMM) was quantitatively synthesized by the coupling of 2-chloro-4,6-dimethoxy-1,3,5-triazine and N-methylmorpholine in THF, and fully characterized. Condensation of carboxylic acids and amines by DMTMM proceeded effectively in THF to give the corresponding amides in good yield.
Graphical Abstract
DMTMM was quantitatively synthesized in THF, and fully characterized. Condensation of carboxylic acids and amines by DMTMM proceeded effectively in THF to give the corresponding amides in good yield.