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The Hive => Novel Discourse => Topic started by: Rhodium on August 20, 2003, 02:24:00 PM

Title: Diazotization/Sandmeyer Reaction in PEG-DCM
Post by: Rhodium on August 20, 2003, 02:24:00 PM

Synthetic Reactions in Polyethylene Glycol.
Diazotization and Sandmeyer Reactions of Anilines in Polyethylene Glycol-Methylene Chloride
Nobutaka Suzuki, Yoshihiro Kaneko, Tateo Nomoto, Yasuji Izawa

J. Chem. Soc. Chem. Commun. 1523-1524 (1984) (https://www.thevespiary.org/rhodium/Rhodium/pdf/sandmeyer.peg-dcm.pdf)

(https://www.thevespiary.org/rhodium/Rhodium/pdf/sandmeyer.peg-dcm.pdf)

Abstract

Diazotization and the Sandmeyer reactions of representative arylamines proceed smoothly in polyethylene glycol - CH₂Cl₂ and have been found to be effective for the preparation of aryl halides and cyanides.