Sarisan from leaves of Piper affinis hispidinervum C. DC (long pepper)Flavour and Fragrance Journal 16(2), pp 113-115 (2001) (https://www.thevespiary.org/rhodium/Rhodium/pdf/sarisan.piper.affinis.pdf)
(https://www.thevespiary.org/rhodium/Rhodium/pdf/sarisan.piper.affinis.pdf)
(retrieved by Ziqquratu)DOI:
10.1002/ffj.957 (http://dx.doi.org/10.1002/ffj.957)
AbstractThe essential oil obtained from the leaves of Piper affinis hispidinervum C. DC was analysed by GC- MS. Sixteen substances were identified, corresponding to 98.9% of the oil. The major component (74.3%) was sarisan (1-allyl-2-methoxy-4,5-methylenedioxybenzene), identified by NMR spectroscopy. Safrole (18.4%) was also found in the oil.
Sarisan (an MMDA-2 precursor, mentioned as "asaricin" in Pihkal) is a relatively rare substance.
Rhode, what's the point that you're trying to emphasize from this article? The fact that long pepper can contain up to 18% safrole, or, that sarisan is similar to safrole? (at least it looks similar to safrole, but I'm no chemist :-P)
abuse
I wanted to tell people about yet another safrole source, but mainly I wanted to inform about the existance of the relatively rare phenylpropanoid
sarisan (6-methoxy-safrole), which is a precursor to MMDA-2, one of the "essential amphetamines", as Shulgin calls them (as they are derived from essential oil components). However, Shulgin uses the alternative name "asaricin" in Pihkal instead of
sarisan.
Edit: The propenylbenzene corresponding to sarisan/asaricin is
carpacin, which is discussed further in
Post 247833 (missing)
(Rhodium: "Carpacin isolation & Physical Data", Chemistry Discourse) and
Post 325672 (https://www.thevespiary.org/talk/index.php?topic=11985.msg32567200#msg32567200)
(Trypstar: "MMDA-2: Carpacin from sesamol", Novel Discourse)Sarisan is also found in several other oils:
Post 324027 (https://www.thevespiary.org/talk/index.php?topic=6025.msg32402700#msg32402700)
(3base: "MMDA-2: sarisan in beilschmiedia miersii leaf oil", Chemicals & Equipment)Post 324777 (https://www.thevespiary.org/talk/index.php?topic=11341.msg32477700#msg32477700)
(3base: "ashanti pepper oil: myristicin, sarisan", Novel Discourse)Post 354928 (https://www.thevespiary.org/talk/index.php?topic=12163.msg35492800#msg35492800)
(3base: "MMDA-2 precursor form long pepper leaf oil", Novel Discourse)Post 380239 (https://www.thevespiary.org/talk/index.php?topic=11563.msg38023900#msg38023900)
(3base: "isoelemicin,sarisan,isomyristicin in lovage roots", Novel Discourse)