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glycine -> MeAm

Started by user1634, July 09, 2000, 01:13:00 AM

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user1634

There were a number of posts on the old board about the glycine ->methylamine reaction...but no rightup on rhod's site!? (ref:search for 'glycine' by hellman under the old novel forum)

Was is a failure in the end? Inferior to current methods? yada yada yada...
A quick search of the new hive comes up blank as far as i can find?


Alphabeta121

i think the tide has turned from hexamine degradation to MeNH2 to the more elegant in situ Nitromethane reduction, alla MM's reductive amination.

alphabeta121


Prdy2GO

I just had to bring up this old post. After searching endlessly for an answer to the question does this or has anyone worked a method to methylamine from glycine?

Don't look at me I didn't do it!

PolytheneSam

One advantage might be that you can get anydrous methylamine  in this process which can be used in alcohol solutions. 

Post 108611 (missing)

(dormouse: "methylamine via glycine(Amino acid) (Page 1) -hellman", Novel Discourse)


Here's an example of the decarboxylation process using sodium acetate to make methane.  Note also the process for making fused sodium acetate which is used in other processes.  I put the top of the next page at the bottom of the page shown below, too (under the footnote).  Try it out and tell us how it works.

https://www.thevespiary.org/rhodium/Rhodium/hive/hiveboard/picproxie_docs/000026411-file_skpk.jpg" title="View this image">


http://www.geocities.com/dritte123/PSPF.html

Prdy2GO

Thank you PolytheneSam,

Some times it is like pulling teeth to get a stright answer out of the hive.
I have done an exaustive search priror to my post and do not have the time at the moment to experiment with a route to Methylamine when I already have  other ways to go. So I am to infer that NO ONE HAS HAD SUCCESS IN GLYCINE TO METHYLAMINE??? Ifyou have please post how it was done or PM me thank you.


Don't look at me I didn't do it!

Rhodium

As far as I have seen, there has only been discussions about it, and noone trying it out.