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THF - GBL (FeSO4)/H202

Started by Belial, April 26, 2002, 06:51:00 PM

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Belial

This was brought up by foxy during an intereting discussion on routes to GBL

"THF (0.5 mol) and 0.1 mol FeSO4 in H2O was treated
dropwise with 1.05 mol 30% H2O2 at (less than)30°C and
the mixt. stirred 3 h at 30°C and 8 h at 45°C to give
61.6% g-butyrolactone."

Would there be room for scaleability here, or would the chance of evil peroxide formation be too great?
Any other perveivable problems with scaling?

Respect
Belial!

ChemicalSolution

Do you have a reference for that?

foxy2

I posted it, UTFSE

Those who give up essential liberties for temporary safety deserve neither liberty nor safety

Belial

g-Butyrolactone from tetrahydrofuran.    
Hara, Hiroshi.  (Japan). 
Japanese Patent  JP  53087347  19780801

As raised by foxy in post # 243627