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Oxyiodination: An Honest Question

Started by Bwiti, September 04, 2002, 08:51:00 PM

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Bwiti

If I was given a huge amount of methamphetamine, plus the Gods gave me the ability to use it without going more psycho than usual and staying up for several days, then I would sign-up for some college chemistry courses. Until then, please try to cope with my questions.
  I have a question regarding an html put on Rhodium's site sept. 4;

https://www.thevespiary.org/rhodium/Rhodium/chemistry/oxone.aromatic.iodination.html

. Can this procedure be used on plain-old benzene? I'm only interested because the products were mentioned to be monoiodinated; iodobenzene can be used in the synthesis of phenylcyclohexylamines, and that's why I care. If not on benzene, then what? Peace! 8)

Love my country, fear my government.

Rhodium

Yes, benzene should give mono-iodobenzene using that particular treatment.

Aurelius

hey Bwiti, need bromobenzene?

Bwiti

"hey Bwiti, need bromobenzene?"

  Does a bear shit in the woods? Yes, I've needed it for over a year!

  Thanks Rhodium. 8)  

Love my country, fear my government.

Rhodium

Bromobenzene can be made in exactly the same fashion, with NaBr/Oxone.

Bwiti

That's sweet! That information won't be useful only to me, since many bees have trouble locating/purchasing pyridine. Also, I'm sure I've bitched before about how expensive it is to have liquid bromine shipped. If any bees don't know what synth I'm talking about, check out pg. 253 of "Total Synthesis 2" - Shame on you if you don't own it. Peace and thanks again. 8)

Pee-Pee S: Of course I wouldn't mind some lab-grade bromobenzene! ;)


Love my country, fear my government.

Aurelius

Hey Bwiti, aurelius has run across a couple of trippin' bears that own a bottle of good size of bromobenzene.  they said that it was useless to them and gave it to aurelius' friend.

Rhodium

No trading at the Hive, just so you remember!

Bwiti

8)

Love my country, fear my government.

Aurelius

Who trades at the hive?

Rhodium