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Fluorinations of phenyl alkenes and benzaldehydes

Started by silenziox, March 31, 2004, 03:36:00 PM

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silenziox

Utility of silicon tetrafluoride as a catalyst of reactions with xenon difluoride: fluorinations of phenyl alkenes and benzaldehydes

Masanori Tamura*, Toshiyuki Takagi, Heng-dao Quan and Akira Sekiya


National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan

Received 29 March 1999; revised 10 May 1999; accepted 17 May 1999. Available online 22 May 2000.

Abstract
Application of silicon tetrafluoride to fluorinations with xenon difluoride as a catalyst is investigated. It was found that vic-difluorination of phenyl alkenes and transformation of benzaldehydes to difluoromethoxybenzenes using xenon difluoride are enhanced by silicon tetrafluoride.

Author Keywords: Silicon tetrafluoride; Xenon difluoride; Fluorination; Phenyl alkene; Benzaldehydes


Would someone fetch the actual PDF as my account doesn't work for some reason  :-[ ? DOI:

10.1016/S0022-1139(99)00103-7



Some editing done  :P  ;) ... "I post these so seldom I didn't even notice the DOI function  ::) .."
"-Yeah, right"



Rhodium

Post 425177 (missing)

(Lilienthal: "Please use the DOI for citations", General Discourse)


In your case, this is the correct DOI:

10.1016/S0022-1139(99)00103-7