Author Topic: Process for preparing benzyllithium: toluene ---> PAA  (Read 84 times)

atara

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Process for preparing benzyllithium: toluene ---> PAA
« on: June 19, 2012, 04:23:18 AM »
http://its.goofyti.me/u/http://www.google.com/patents/US20060170118

Benzyllithium -- or benzylsodium -- reacts easily with CO2 to give PAA (lithium phenylacetate, obviously). The only missing link now is DMSO...

Ferrum

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Re: Process for preparing benzyllithium: toluene ---> PAA
« Reply #1 on: June 19, 2012, 04:34:39 AM »
http://its.goofyti.me/u/http://www.google.com/patents/US20060170118

Benzyllithium -- or benzylsodium -- reacts easily with CO2 to give PAA (lithium phenylacetate, obviously). The only missing link now is DMSO...

Available all over the place for great prices almost anywhere in the world. Under its real name even, as a pain relief agent for arthritis or numerous other uses. 99% DMSO in 1% water for about 10 bucks a liter...cant get much better than that!

A fun little tidbit about DMSO for any that might read. If your pour it into the palm of your hand, there is a good chance it will pour out the other side in a few seconds. Needless to say this allows it to take nearly anything that is on your skin and make it sink in to your system. Use this for dermal drug delivery, etc. (ex: place pain killer drug on aching knee, pour DMSO on it, knee feels better). Beware of sucking bad reagents into your skin however...

atara

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Re: Process for preparing benzyllithium: toluene ---> PAA
« Reply #2 on: June 19, 2012, 04:39:03 AM »
Mmyeah, goes right through ya. It's like HF, only without the "deadly" and "corrosive" bits.

carl_nnabis

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Re: Process for preparing benzyllithium: toluene ---> PAA
« Reply #3 on: June 19, 2012, 04:02:57 PM »
A fun little tidbit about DMSO for any that might read. If your pour it into the palm of your hand, there is a good chance it will pour out the other side in a few seconds. Needless to say this allows it to take nearly anything that is on your skin and make it sink in to your system.
very cool, i did knew it and everything dissolved too become absorbed, but not that it comes actually out ;D
BTW wasnt it DMSO that caused the incident hoffman had to discover LSD-25 as hallucinogen?
A lot of people think it becomes absorbed transdermal as it is, but look how the clandestine fentanyl cook has to protect himself, as his product is the same potency like LSD, few other hallucinogens, few cannabinoids etc...
but these arent really toxic compared to their effective dose which is way more than thousand times higher unlike fentanyl, which is also not absorbed readily through skin
"It's like the drug trip I saw when I was on that drug trip!"