FCA is favorable over Grignard, no need for Mg and no Bromination, but where to get water-free AlCl3? Also the highly acidic Conditions tend to mess up some substituions. The new research showing that Graphite can substitute Lewis Acids (note that there are no acidic conditions involved now!) - with the drawback that only carboxylic acid halogenids work. So what to do with this extra oxygen? Acryliy acid halogenid and reduction? Reducing the Oxygen completly isnt really an option IMHO. So why not use Propionic acid chloride, reduce the Ketone to the alcohol, then dehydrate to the propenyllbenzene. The reduction to the alkohol could be done in good yields with electrolysis.
Please let me hear you opinion (also, if you have refs with details on the electrolytic reduction - feel free to contribute)
Please let me hear you opinion (also, if you have refs with details on the electrolytic reduction - feel free to contribute)