Author Topic: proposed NaClO chlorination of aromatic amines (Read 59 times)

poisoninthestain · « **on:** July 16, 2009, 08:55:58 PM »

http://www.erowid.org/archive/rhodium/chemistry/5-chlorovanillin.hypochlorite.html

...supposedly works for disubstituted benzaldehydes to form a monochlorinated product.

My question is how this will work on aromatic disubstituted amines *cough* 2C-H...

I'm planning on testing this out sometime in the near future.

I assume it will form the hydrochloride salt of 2C-C as well.

Sedit · « **Reply #1 on:** July 16, 2009, 09:14:11 PM »

Im not 100% on this but wouldn't the amine react with -OCl to form the chloramine derivitive.

However this seems like this text could make a good addition to the vanillin to 5-hydroxy vanillin(AKA The iodination of vanillin)threed seeing as how it will form the 5-chloro vanillin in 90% yeilds from nothing more then Sodium hypochlorite.

Author Topic: proposed NaClO chlorination of aromatic amines (Read 59 times)

poisoninthestain

proposed NaClO chlorination of aromatic amines

Sedit

Re: proposed NaClO chlorination of aromatic amines