Author Topic: Lab Accidents  (Read 2279 times)

psychexplorer

  • Subordinate Wasp
  • ***
  • Posts: 138
Re: Lab Accidents
« Reply #140 on: June 01, 2011, 08:52:42 PM »
It all depends on the reaction. Ruined glassware is preferable to a Hg volcano or a runaway nitration.

All the more reason to encourage people to study the reaction carefully, understand what is going on, and what could go wrong before making a practical attempt. Writeups are summaries of past experience, not a ready-to-go chef's recipe.

psychexplorer

  • Subordinate Wasp
  • ***
  • Posts: 138
Re: Lab Accidents
« Reply #141 on: June 01, 2011, 08:57:51 PM »
I dont disagree with this comment at all as i understand it, but i would love if you gave a full version of what you mean by this?


It's a common saying roughly analogous to, "Garbage in, garbage out."

Poor setup and poor workmanship should be expected to yield poor results. That could be a loss in yield, a failed reaction, undesirable side products, contamination, or a nasty accident.

karatekid

  • Larvae
  • *
  • Posts: 0
Re: Lab Accidents
« Reply #142 on: August 17, 2011, 07:02:33 PM »
Quote
The end results from the effort applied

Lugh, you have my full respect, i know you have been around since the war, (on drugs)

I dont disagree with this comment at all as i understand it, but i would love if you gave a full version of what you mean by this?


He means the more you put into something, the more you will get out of it.  And of course the contrapositive applies.

Tsathoggua

  • Autistic sociopath
  • Foundress Queen
  • *****
  • Posts: 662
Re: Lab Accidents
« Reply #143 on: August 18, 2011, 12:29:46 AM »
You get out what you put in basically. It goes for precursor reagent to end product also. Garbage in, then garbage is what one gets out.
Nomen mihi Legio est, quia multi sumus

I'm hyperbolic, hypergolic, viral, chiral. So motherfucking twisted my laevo is on the right side.

b6baddawg

  • Larvae
  • *
  • Posts: 35
Re: Lab Accidents
« Reply #144 on: October 11, 2011, 09:46:16 PM »
i put trays on the side to catch spillages rather than shit go all over.
sounds smart yeah? 8)
then i tip over a gallon of 25% naoh solution at 80c over the hotplate, ok the tray caught it all...
flooded the plug at the back of the hotplate and.. kerpow
so while the thing zapping like frankenstein laboratory some stupid idyut turned the wrong plug off on the wall and nearly grabbed the hotplate while it was still zapping away.
the mains fuse then blew just before i touched it, and probably saved my life.
i realised when i replaced the fuse and it blew again straight away that id turned off the wrong plug.
not so clever lol


Dr. Tox

  • In Stasis: See You In A Few Years!
  • Subordinate Wasp
  • ***
  • Posts: 145
Re: Lab Accidents
« Reply #145 on: January 12, 2012, 11:33:18 AM »
Slipped and dumped the container of GBL, all at once, into the 5 or 6 liter beaker with the heated, stirring lye.

....I thought "Oh shit"... but everything appeared ok for about 1 minute, then I had molten Gamma Mt. Vesuvius Butyrate exploding all over the kitchen. My partner & I saw it starting to boil and executed a perfectly synchronized, television worthy slow motion double swan dive straight out of the kitchen and into his computer desk's alcove together and did the whole duck & cover routine. 

It ate: The Stove. The Linoleum flooring. The ceiling. The microwave. The cat dish & food. The countertops and finally, it stripped the paint off the refrigerator. Luckily, it didn't eat the cat who evidently had enough sense to stay the fuck out of there at that particular moment.

When the kitchen cooled off enough to enter and clean up, we began sliding the appliances back into their places and the linoleum flooring scraped up off the subfloor like algae under a razor.

We lost about half the product and wound up with about 5Lb left over as a consolation.  ;D

When I was about 13 and in my father's lab, I reached over to grab a small distillation flask to examine the red liquid inside.... A hole, crack or some other thing turned it into the chemistry version of a dribble cup. About 15 ml or so of what I suspect to this day was phenol, ran straight down my right arm, soaking immediately into the flesh and searing right through the nerves, leaving a raised white welt wherever it touched, which freaked me well & truly out.

I didn't touch my dick with that hand for a week.

Another time when I was about 15 or so, I reached over with evidently lye dampened hands (or something) to grab my Dad's 1L RBF full of freebase amine by the neck, which promptly wound up draining through the cracks in the flooring we were standing on.... Note to self: Never grab glassware before you check yourself for lye....

Around the same age, while on a heavy amphetamine bender with my father, we spent a couple days working in the basement only to come up and find that the air upstairs was not nearly as acrid & smokey as the air downstairs. AFAIK, we'd been working in a cloud of HCl.

Also around that age a partner of ours was swirling something (I don't recall what) in a graduated cylinder when it suddenly became overly energetic and took off out of his hand like a rocket and past my face, smashing into the far wall. Whatever it was smelled like bananas.

The trio of us once again in the backyard shed, awake for several days, sitting around a reductive amination. Me sitting on a box (or a steel can of that evil red phenol shit that sank into my arm), my Dad on a Sanke keg and our partner on a stool. All of us doing the sleep dep nod.... My Dad, being fat, falls off his keg, kicking shit all over the place, waking our partner up and being somewhat neurotic at the best of times, spazzes out and with thrashing arms singlehandedly obliterates flask & glass bead packed, double column assemblage in a swath of destruction, the likes of which, thankfully, are rarely witnessed. The collective commotion & emergent projectiles sent me nearly to the roof to cling for dear life.

I came home from school one day to find a chlorine ground cover above the backyard lawn, which died shortly thereafter....

Another time the partner gassed us and the neighbors, with something that smelled strongly of sewage...

Eventually that shed did spontaneously combust in a final suicidal act and investigations by law enforcement were hotly pursued, yet ultimately fruitless due to the efficiency with which the shed immolated itself. That shed was hexed and killing itself was the only honest thing it ever did.

But we did have brilliant emerald green puddles in the back yard dirt every time it rained heavily. I'm still not sure what it was.... a chromic compound perhaps?
« Last Edit: January 12, 2012, 12:44:31 PM by Dr. Tox »
Alimentary, dear Watson; I had a gut feeling.

tryl

  • Pupae
  • **
  • Posts: 89
Re: Lab Accidents
« Reply #146 on: January 12, 2012, 02:14:59 PM »
LMAO!!
"In the words of Archimedes, give me a lever long enough and a place to rest it... or I shall kill one hostage every hour."

nigluhS

  • Pupae
  • **
  • Posts: 81
Re: Lab Accidents
« Reply #147 on: January 12, 2012, 03:49:54 PM »
Sand just takes so much longer to heat up vs oil.

can you zap it in the microwave to get it heated up quicker? Not HOT, but warmed to a point where the burner can take it from there?
when the wasps and the bumblebees have a party, nobody comes that can't buzz...

tryl

  • Pupae
  • **
  • Posts: 89
Re: Lab Accidents
« Reply #148 on: January 12, 2012, 07:19:44 PM »
i've once had a 30lit carboy full of basifying mimosa bark break open and flood the apartment & down the stairs the floor below & didn't notice it for a few hours until i woke up from my beauty G sleep.

i've had a few dumb minor accidents here and there, mostly spills, but nothing of the epic proportions like some of the stuff mentioned here.
i mostly remember the one where i ruined ~10gr of morphine. that's mostly because after that i wanted to break some stuff and then curl in some corner and cry.

antibody's 2CB one is truly the stuff of legend. :D

"In the words of Archimedes, give me a lever long enough and a place to rest it... or I shall kill one hostage every hour."

Dr. Tox

  • In Stasis: See You In A Few Years!
  • Subordinate Wasp
  • ***
  • Posts: 145
Re: Lab Accidents
« Reply #149 on: January 12, 2012, 10:42:20 PM »
"We'll Make Better Mistakes Tomorrow!"
Alimentary, dear Watson; I had a gut feeling.

zgoat65

  • Subordinate Wasp
  • ***
  • Posts: 103
Re: Lab Accidents
« Reply #150 on: March 03, 2012, 09:30:56 PM »
I hate talking about the SnB, but my biggest lab accident came from thia rxn.  Having done many successfully, I got lazy and loaded the bottle I intended for the gas pump with the rxn conponents (this bottle had been used in gassing before and was a little thinned out in hindsight).  Anyway, the rxn kicked off, and started to run away very quickly.  I attempted to vent, but more NH3 was being produced than the bottle could vent.  Within 30 seconds, I grasped the top to try to get more venting and the bottom blew out in flamethrower fashion.  Engulfing my pants in flames.  Luckily, there. was a fire extinguisher right next to me, and the flames were extinguished quickly.  I made it out with NO burns and no calls to the local fire dept.  Once it was all out out and under control, I assessed the damage, and found the only thing amiss was that my eyelashes were missing.  That was my last SnB.  Birch may take a little longer, but IMHO is much safer.
If you build a man a fire, he'll be warm for a day.
If you set a man on fire, he'll be warm for the rest of his life

Dr. Tox

  • In Stasis: See You In A Few Years!
  • Subordinate Wasp
  • ***
  • Posts: 145
Re: Lab Accidents
« Reply #151 on: March 04, 2012, 01:53:59 AM »
No mas pantalones?  :P
Alimentary, dear Watson; I had a gut feeling.

Tsathoggua

  • Autistic sociopath
  • Foundress Queen
  • *****
  • Posts: 662
Re: Lab Accidents
« Reply #152 on: March 14, 2012, 04:44:45 PM »
Shit, tox, some of those had me in stitches.

GBL explosions are ugly. real ugly. Especially when they vent like an exothermic motherfucking krakatoa, all over the show, splattering NaOH, MeOH all over the kitchen.

Never, did Toady stop being grateful that he didn't A-lose an eye, as it would happen when it scratched his fucking nose wouldn't it. B-that the cat was out, C-that his parents had absolutely no fucking idea it had even happened, and D-he even managed to save a pound or two.

He can't stand the smell of lactone now, anymore than he can stand the smell of hypochlorites..............................................................

He still has crap sight in that eye. And oh boy, the language that got used......Toady is very surprised he didn't get any worse out of that one...that could have gone nasty.
« Last Edit: March 14, 2012, 05:12:24 PM by Tsathoggua »
Nomen mihi Legio est, quia multi sumus

I'm hyperbolic, hypergolic, viral, chiral. So motherfucking twisted my laevo is on the right side.

jon

  • Foundress Queen
  • *****
  • Posts: 1,883
Re: Lab Accidents
« Reply #153 on: March 15, 2012, 06:19:34 AM »
exothermia is what happens when you are'nt paying attention

Tsathoggua

  • Autistic sociopath
  • Foundress Queen
  • *****
  • Posts: 662
Re: Lab Accidents
« Reply #154 on: March 15, 2012, 07:56:00 AM »
Yeah, childhood mistakes etc. Shit happens, glad he was able to recover some yield, and that nobody else got injured. You shoulda seen the way the geebee erupted from the long-necked kjehldal flask it was refluxing in. Oh jesus. Lactone everywhere, NaOH blasted out of the column....A sudden flash boil, with a WOOMPHH!!! all the solvent evaporated at once and launched enough lactone into to atmosphere of the kitchen to do funny things to the plastic surroundings.....
Nomen mihi Legio est, quia multi sumus

I'm hyperbolic, hypergolic, viral, chiral. So motherfucking twisted my laevo is on the right side.

fresh1

  • conspirator
  • Dominant Queen
  • ****
  • Posts: 339
Re: Lab Accidents
« Reply #155 on: March 28, 2012, 07:18:38 AM »
Quote
can you zap it in the microwave to get it heated up quicker?

 nighulS a bit (a few mm) of water works a treat as the steam convects the heats throughout the sand and quite quickly too ;)


 fresh is cleaning some oily things with acetone at a friends parents place...they are supposed to be gone until the next day, so the elves have come out to play (expensive secure eviroment etc)

 has about 500mls of acetone in a stainless steel bowl which is on a big chest freezer with the door on the top

  Almost finished, probably has about 20-30gms of 'oil' in the acetone when he goes to pick up a rag off the floor...well, as he bends over, and he reckons he couldn't have done this if he tried ,, his arse somehow bumps the lid of the freezer so it springs open distributing olefin ALL over the wall, the acetone evaporates in no time and he's left looking at a ketone painted wall :o

  ok thats a bitch but it can be scraped off, it will just take some time, unfortunately as fresh and his mate are admiring the art and discussing the best way to try and recover the oil....his (very straight) parents come down the driveway :o

   did we panic?  er yes, more like PANIC as we suddenly found ourselves with about 60secs to make the kitchen look like a kitchen again..fortunately this dude and fresh are almost telepathic and it was clear this was no time for talk

The friend starts grabbing anything suspicious and starts taking it anywhere but just inside the backdoor where his folks are about to enter, while fresh freaks and with a heavy heart, quickly soaks THE rag (culprit!) and quickly wipes the wall clean,
  appearing from behind the freezer to mr and mrs friend who says to us "well thats a sight for sore eyes.." f1 didnt know what to say coz he didnt know what she was looking at....heart in mouth, slack jawed, oily rag in hand, time slowed to a standstill  . . .

and....nothing! somehow we had made it look like we had decided to clean the kitchen and mrs friend wasnt complaining..



  Another time in a galaxy far far away, fresh and his grrrl decide its hydro time and spent much time and money establishing a "hidden in plain sight" growroom we nickname 'alice'...coz walking into it was like going into wonderland! 8) Its got it all including CO2 systems etc but it rocks...

This was in an oldish (1940's) second floor apartment with wooden floors.

Its a 2.8x3.6mts grow with micro irrigation on rockwool and a 100 litre reservoir at the low end (which the grrrls drank more than half of each day!)  This reservoir is made from thick black builders plastic in a wooden frame, with no base, the plastic sat on the carpet.

  In the reservoir were a pump and an aquarium heater set to IIRC about 24c and for a few months, its all good

   Then, one morning fresh hears knocking at the back door and goes to find his downstairs neighbor asking "if" maybe we had had some kind of flood to which I reply 'no, why?' He then takes me down to his flat and into his so he tells me, newly painted bedroom...

     much to f1's astonishment, he sees the contents of the reservoir drippin off this dudes ceiling, and rapidly starts searchin for some plausible reason for this, which doesnt implicate fresh :P
    He remembers the night before was a crazy thunderstorm and goes off into some "its so unbelievable it must be true" account of the
REALLY BAD leak in his lounge which somehow had found a way into his bedroom  :o which IS a bummer BUT he was already discussing repairs with the agents...and doubted this would happen again....

    Making excuses to run away fresh nips up to alice to see wtf and finds the heater has someho dislodged itself and had fallen to the bottom of the reservoir and had melted through the plastic and watered old mates bedroom :o

  There was no way he was going to pull the crop over this shit, but was definitely a touch more paranoid for the next few weeks, and as it was xmas wanted to visit some friends in the bush and so left alice in the care of a mate...who didnt bother to do shit, so fresh comes home to a mature crop with maybe 10 days to go, in the process of dying...NOOOOOOOO!!!!

Once again panic as he tries to resuscitate the plants every way he knows, only to slowly realise his efforts are in vain and has no choice but to harvest.
       Could have been worse, still got about 1.3kg dry ;D  and learnt a LOT about indoor growing 8)
"Curiosity is a gift"

Tsathoggua

  • Autistic sociopath
  • Foundress Queen
  • *****
  • Posts: 662
Re: Lab Accidents
« Reply #156 on: March 28, 2012, 10:55:36 AM »
Toady would have been strongly inclined to cockslap the shit out of the shouldbee caretaker. He has had the same thing happen to him, when he got banged up, only in his case it was perhaps even worse. Lost 7-8 yopo trees, a peruvian torch , Datura (D.ferox, or possibly D.innoxia), Some sinicuichi and Peganum harmala...the latter two are very hard to keep alive when they are young, so he could have forgiven their loss through simply not knowing how to treat them. Syrian rue needs VERY little water, at least when young, never managed to get them beyond an inch or so himself, even watering by the drop or two from a burette, using agents to both accelerate and slow the growth...but every single one of his plants died through sheer and utter negligence. None got so much as a drop of H2O or speck of fertilizer over the entire 8-9 months.

The person responsible agreed to look after Toady's plant collection, and simply didn't. He was gutted after the effort he put into raising his cohoba trees from seed, they had become over 3 foot tall, some even bigger, save for one that grew naturally with a curled kink in the stem, which was to stay as a bonsai, Toady was absolutely gutted to lose all his plants. Weed is one thing, but all his exotics........           
Nomen mihi Legio est, quia multi sumus

I'm hyperbolic, hypergolic, viral, chiral. So motherfucking twisted my laevo is on the right side.

fresh1

  • conspirator
  • Dominant Queen
  • ****
  • Posts: 339
Re: Lab Accidents
« Reply #157 on: March 29, 2012, 01:19:09 AM »
thats sad to hear toady mate.  I think my friend had some paranoia issues but still he should have said yes and done no!

the loss of plantlife is bad enough, but being let down by someone who "promises" has its own pain :'(
"Curiosity is a gift"

carl_nnabis

  • Subordinate Wasp
  • ***
  • Posts: 245
Re: Lab Accidents
« Reply #158 on: May 27, 2012, 03:57:19 AM »
Read this a few days ago, but reading doc tox story just made me speechless... There is some sort of chemical horror involved i really can understand and relate to somehow...
But, anyway, I wanted to tell the story of a poor little bee that really has fucked up a lot of his work: This poor little bee hadnt a flask big enough to these days, so he decided to make some amount of amphetamine in a series of small reactions, and reduced every night for about one and a half week like 25g p2np, collected the freebase and precipitated after drying the solvent the sulfate salt in the afternoon.
After that time he had collected a half-full marmelade glass of amphetamine-sulfate, to finally distill it for greatest purity. After he set up his glassware, had the amphetamine based and heated and first drops of smelly oil started to appear in the receiving flask, he got really excited and turned the radio standing behind his setup louder...
Wearing a lab coat, because he always does when working with concentrated sulfuric acid, his sleeve got caught on his setups stative, and everything, condenser, claisen two flask AND the hot lye/amphetamine solution everything fell on the floor, broke and after standing like five minutes shocked there, he cleaned himself from a few lye splatter (thank you labcoat, but i still hate you for this whole thing!), he dropped down on a big bucket and started to cry like a little baby, knowing he just had destroyed like nearly two weeks worth of hard work and glassware worth nearly 100€...
I myself hadnt that much really concerning failures made, once i spilled bromine over my unprotected hand, it didnt do anything as it was washed away really quick, but had like a half week a colored spot like iodine, nothing to worry about.
But I have destroyed a lot of clothes with tiny little unseen spills of lye, or even worse, sulfuric acid. You just dont take notice of them, you see these first when its already to late, after washing mostly  ;D
Let me think... Oh one time a empty bottle of denatured alcohol exploded, when i was about to make some cyanate salt with a (spiritus) burner, i filled it up, put the empty bottle besides and put the flame on. Beeing outside, i stood up to get the urea/carbonate mixtur ready to heat, and the empty botte fell over, having the opening directed to the burner...
Filled with ethanol vapour mostly and with a really small opening, the flames set the vapour inside on fire, and the bottle exploded   ;D
I sat immediately on my ass, nothing happened because i was in the garden but i was a bit shocked anyway.
« Last Edit: May 27, 2012, 09:16:07 AM by carl_nnabis »
"It's like the drug trip I saw when I was on that drug trip!"

Sydenhams chorea

  • Pupae
  • **
  • Posts: 97
Re: Lab Accidents
« Reply #159 on: June 10, 2012, 07:34:20 PM »
Shit, shit, fuck, I want to cry right now.

I shouldn't have worked in the lab, I was very tired due to lack of sleep. Or I should have finished that one thing and gone to bed, but no. While another experiment was refluxing in an oil bath I took a small flask in which was made a small 1.5 gram batch of DET by ethylating tryptamine à la Shulgin, but was stirring for a week instead of 36 hours. A nice yellowish brown solution was obtained with white solids on the bottom, it looked promising.

I just performed a TLC on the solution and compared it with a commercially obtained tryptamine standard. Plates were silica gel, eluent was methanol/NH4OH(strong) 100:1 and it was visualised with the modified Erhlich's reagent.

A single spot of Rf 0.59 was obtained, close to the reported value of 0.65 using this solvent system. Tryptamine standard was 0.32 by the way.

Yes a single, beautiful, promising violet spot, you heard it right. (The tryptamine standard spot turned reddish-violet after a couple of minutes). Then I decided to strip off the solvent, turned around, slipped and, goddamned, the little flask fell out of my hands right into the hot oil bath (130°C), producing a loud cracking noise and a small geyser of oil.

I want to kick myself so hard.
« Last Edit: June 10, 2012, 07:36:49 PM by Sydenhams chorea »
It is perhaps the narcotic. Hyoscine affects certain people very oddly. One cannot be sure. Sometimes, these cases take strange forms. The victim becomes in a sense, 'mediumistic', a vehicle for all the intangible forces in operation around her.