Author Topic: Sassafras root bark  (Read 645 times)

German

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Sassafras root bark
« on: February 09, 2010, 08:27:36 PM »
I walked into my health food store the other day and saw that they sell pounds of both raw sassasfras root bark and also grinded up sassafras root bark powder. Has anyone steam distilled essential oils before? Do you you think it would be worth trying?

NeilPatrickHarris

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Re: Sassafras root bark
« Reply #1 on: February 09, 2010, 09:39:14 PM »
depends on how well sealed and how old the bark is.  if you buy one definitely go with the root bark chips instead of the powder.  essential oils are volatile, so if it's ground up to a powder then you're liberating more of the oil to the air where it can evaporate.  the chips keep more oil trapped in the bark.

but when you steam distill it definitely helps to toss it in a blender and grind it to a fine powder only right before you put it in the still, this way the steam doesn't have to penetrate the wood and to put it simply you can steam distill faster.  if it's decent root bark you can get ~15ml per 1lb or at least that's what swim always averaged with dry root bark chips of good quality.  the bark was spent within 1.5-2 hours but dealing with the hydrosol is a real bastard not to mention swim's still could only fit 200g of material at a time.  so swim had to steam distill several times just to get a measly 30ml of oil from 2lbs root bark.  to deal with the hydrosol swim would put it in the fridge to get better separation b/c the oils' density is fairly close to that of water.  also you'll get little oil globs that cling to the glass and sometimes surface tension would keep a thin layer of oil on top of the water but for the most part... 90% of your oil will be at the bottom.  swim could fit his sep funnel in the fridge, so he stoppered it to keep the smell contained and put it in the fridge and patiently wait and agitate it from time to time to get the oil globs clinging to the glass to fall to the bottom then tap off the oil layer on the bottom.  it takes a lot of patience dealing with hydrosol cuz you want every little drop.

the short answer to your question is... if you feel that the #'s given above are worth your while and the root bark is either sealed really well (some is nitrogen packed for ultimate freshness) or pretty fresh then go for it... but go with the chips not the powder.  make it a powder yourself right before steaming.  swim has gotten as low as 7ml from 1lb and as high as 23ml from 1lb although most of the time it was almost always 12-15ml
« Last Edit: February 09, 2010, 09:59:44 PM by NeilPatrickHarris »

poisoninthestain

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Re: Sassafras root bark
« Reply #2 on: February 09, 2010, 10:41:44 PM »
I steam distill a lot in the summer when the trees are easily dug up but I've only used commercial bought bark once...for the price i didn't find it worthwhile. The yield digging up roots is leaps and bounds ahead of store bought sass bark. I know Sedit can vouch for this one. Throw the bark in a pressure cooker, and nigga rig a hose of some kind to the top...biomass vessel in 40 seconds. Then I just feed the hose into my condenser and distill like normal. A supersaturation of salt helps bring the hydrosol out of the aqueous layer but unless you're workin with A LOT of hydrosol it's not worth the added effort.

Sedit

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Re: Sassafras root bark
« Reply #3 on: February 11, 2010, 08:36:01 AM »
Extract the hydrosol with Dichloromethane which can be stripped with ease without damaging your results. This will save you much time and increase yeilds by thining it out and not allowing those pesky globs on the side. The freezer is still not a bad idea even when using DCM.
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Re: Sassafras root bark
« Reply #4 on: February 12, 2010, 02:55:57 AM »
You might want to check out "mexican pepperleaf" or "hoja santa", piper auritum. It made strikes book for a reason. Everywhere it can grow it is a weed. The plant will take over your house if you live in SoCal, the humid south, or I bet it would do well in a pot but to really see the monster go and get enough of what you are after it has to be in the ground in the sunshine. You will be steam distilling just to get it ready for composting. They sell it in little bags in Mexican areas for making food. As NeilPatrickHarris pointed out, because the target is so volatile the bags aren't any good. But that place will know someone that has it live. Fresh just tastes better! Long story short, you break the plant into sections of 2 nodes or more and baby it with high humidity untill it roots and you are in. No joke, safrole forever. Freeze the leaves and go.

NeilPatrickHarris

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Re: Sassafras root bark
« Reply #5 on: February 12, 2010, 03:20:48 AM »
Freeze the leaves and go.

swim never had much luck with freezing fresh leaves, the natural water present in the leaves would freeze and burst cells that made steam distillation much less effective, at least in swim's experience.  surprisingly chlorophyll distilled over (was green and smelled kind of like grass in addition to the essential oil).  perhaps leave the leaves intact and set them out for 5-7 days first to dry them out, just long enough for them to get dry but should still retain most of the EO as long as they haven't been broken up yet.  then after they're dry, vacuum seal and stick in the freezer.  after defrosting then break them apart as disposable stirbar said and steam distill.  has anyone else had problems freezing fresh plant material?  swim finds that the cell structure always breaks down so you must eliminate the natural water first before freezing

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Re: Sassafras root bark
« Reply #6 on: February 12, 2010, 07:53:34 AM »
If you are getting chlorophyll in the reciever then best to pack a small colume ahead of the condenser with a small amount of glass wool. The chlorophyll is not distilling over persay but is being contained in a mist from rapidly boiling mixture. The wool should solve this issue 99% of the time.
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NeilPatrickHarris

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Re: Sassafras root bark
« Reply #7 on: February 12, 2010, 01:00:59 PM »
If you are getting chlorophyll in the reciever then best to pack a small colume ahead of the condenser with a small amount of glass wool. The chlorophyll is not distilling over persay but is being contained in a mist from rapidly boiling mixture. The wool should solve this issue 99% of the time.

thanks for the tip, swim probably won't ever have that happen again cuz it only happened to him once when he was trying different things and will never try that way ever again b/c it sucked.

swim just always assumed it was due to his preparation of the leaves beforehand.  this was back when swim was just learning how to hydrodistill/steam distill and was trying a number of different ways of preparing the leaves to see what worked best.  the chlorophyll incident only happened once and it was from this workup: he froze fresh leaves, he assumes the natural water present expanded when it turned to ice causing the plant cells to break, when he defrosted the fresh leaves he noticed they were really limp.  the shredded them up, this made a green slurry of sorts, he then hydrodistilled that with water.  he was just trying different ways of trying to get as much EO out of the leaves as possible.  but he assumed that this time he just ended up releasing the photosynthesis chemicals, making them available to be steam distilled as well side-by-side with the essential oil.  this is instead of the typical "sweating the essential oil out of the plant matter" approach.  now swim realizes that anytime you freeze fresh leaves they come out limp and swim's yields were always low.  by drying them out first (then freeze if necessary to store them for awhile) then crushing up the dried leaf and steam distilling that would seem to be the best technique as the leaves are still aromatic when dry.  or just cut up the leaves when fresh and steam distill them that way.  definitely don't make a green milkshake out of the leaves first lol, that doesn't work so well with fresh leaves but works great with dried root bark

now swim uses a setup exactly like poisoninthestain describes, a PC for a still (material suspended above the water) then copper tube coming out the top of glass condenser, vac adapter, receiving flask.  works great as long as you can keep all the leaks sealed, those f'ing leaks are the killer and always seem to happen after enough uses.

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Re: Sassafras root bark
« Reply #8 on: February 12, 2010, 02:52:39 PM »
I had read up on the "dry basket" with non condensing steam flying around it but thought that if I was to get every drop I was going to need every cell wall broken and the stuff like soup. I hand blendered the stuff in a modified pressure cooker of doom. Also These leaves are big and flat. Even dried, cut into strips I just wasn't seeing how steam was going to go all around every part and get it all. Remember, this isn't rosemary or lavender where steam can rip right through.

And from the soup, I remember the product looking pretty amazing right off the bat. I don't know what I was doing to not get super chlorophyll oil. Solvent in the sep receiver, drying then vac fract distill and it was perfect. The only part that isn't perfect is the amount of work for so little. The smell will get to you after a while, also. I was circulating ice water and it still loved up my house.

I said little bags, because they only have a few leaves. In the bags the leaves are like the size of your two hands flat next to each other, but on a big plant in the ground they are more then a foot long.

I don't know what tech was being used for drying. These leaves as they come off the plant are almost all water. They also reek of safrole. No shit. You handle the leaves in any way and you smell like (m)honey. I was interested in the least amount of loss and the most extraction. Please, someone tell me/us the way.

I never got around to it, but perhaps will soon, but old hippy pot cooking tech is to float a high boiling non polar(cooking oil) on a big pot of water and toss in all your trim from your plants and boil away. Auto temp control 2 phase extraction. Might be just the ticket to making your neighborhood stink like a community college kids e lab. Distilled peanut oil?

Since this is of interest, I will point out again that this is a traditional ingredient in Mexican cooking. Being that it is a traditional flavor, and in parts of the US a weed, lot's of said Mexicans mothers/grandmothers either have the plant or have a friend with the plant. The stuff takes off like golden pathos. Seriously, get as big a piece of it as you can, rip the leaves off the 2 bottom nodes and toss it in a water bottle. When you get home put it dirt, water & mist it, put a plastic bag over it not air tight, and put it somewhere comfortable for a couple days. Then start moving it towards light. When the leaves don't wilt when you leave the bag off you are money.

In spring I have broken pieces off and stuck them in the ground outside with no bag or sun protection, they wilted to the ground for a few days then took off. This stuff is tough like the grandmas cooking with it.

I found it from people who had it. I didn't even have to buy it. I'm sure someone sells it live online. I have no recommendations or knowledge of vendors or raising from seed. I just typed the latin name in and the first google result has info and seeds. I have never seen seeds from it. I also have seen that with lots of water it seems to prefer sun/side of house areas where as that site says shade. It is tough. Put it everywhere and see where it grows :)

That site is talking about root division. Huh? Yeah, they make plenty of plantlets, but the real deal is knocking off a big branch and making 10-20 plants.

Also know what you are getting into. Even with a big plant that has a high concentration of what you want, you still have to process a shitload of it. But if you want to be off the radar and know your oil(and eventually crystals) was loved up from the start, this will get you there.

Sorry to derail sassy root bark thread. If this should be clipped and moved, whatever...

Vesp

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Re: Sassafras root bark
« Reply #9 on: February 12, 2010, 11:45:13 PM »
This plant is much more interesting, thanks for sharing all of the info about it  ;D
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Re: Sassafras root bark
« Reply #10 on: February 13, 2010, 01:31:45 AM »
Since more people are asking...

Where I was at the time never froze but all the info says it is not freeze hardy. I would believe them.

I also would believe that if one kept a "mother" indoors and in winter chopped up nodes to have plants ready to plant in spring, you would probably be stoked. This is all just guessing, because like I said, mine lived outside. But it grows fast. Or when it's end of season, knock all the leaves off and just plant up the broken up nodes and bring them inside to grow out all winter in a terrarium or whatever.

Get creative! You guys are smarter me.

I would actually like to hear better ideas for the steam extraction. These leaves are a big wet mess and I typed how I dealt with them. One thing I never tried was super heated steam. Just would pop off the still head and fill er up every once and while when it felt low when rocked.

I think that if you all have questions, ask them here. Sometime down the road it could help someone else. And helping people make more real deal is awesome.

Next up, Acorus calamus gardening and extraction! You kids have work to do!

"Awesome pond. I like how you planted it."
"Yeah, I made an artificial wetland to handle the waste treatment for the fish."
"Cool."
"You wish you knew how cool..."

EDIT---> I forgot to point out the important non-polar, floating on water, in the receiving sep funnel. It stops all that hydrosol little effing globs of oil stuck everywhere bs and lets you drain the shitloads of water that come over. I typed it, but it deserves mention again. Save yourself the hassle. When you are working hard for it, it is way not cool how nice your unrinsed glass smells. Sure it aint much, but dammit it will piss you off to not get every bit.
« Last Edit: February 13, 2010, 01:45:25 AM by disposable stirbar »

Vesp

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Re: Sassafras root bark
« Reply #11 on: February 13, 2010, 02:32:09 AM »

I'd make something like this: http://www.pelletlab.com/blog#lavender


This should be easy to do if you've got a big pan that seals or a pressure cooker thing -- or that you can make it seal with a little bit of work - plastic and clamps?


I figure a nice little metal grid of some sort supported above a boiling solution of water would do wonders, esp. with once frozen plant material.



The trickiest part might be to collect the steam, but with a bit of drilling, decent temperature resistant putty/glue and some unreactive tube for leading into a condenser.. you'd be in great shape. Right?

I've never done it this way, but I have distilled sage brush oil via semi-ghetto rigged glassware... but I can't see any problems with this idea....
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Re: Sassafras root bark
« Reply #12 on: February 13, 2010, 07:05:33 AM »
Root bark, sure. Floppy leaves? I didn't think so. That is exactly what I was typing about. I have seen a number of the basket above water or superheated steam chamber essential oil distillers pics. You will see. Toss a bunch in that machine and you would have a big mass with vapor going around the sides. I still don't see it working right.

If you build a super critical co2 machine you could also make aerogel, I think ;)

jon

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Re: Sassafras root bark
« Reply #13 on: February 13, 2010, 07:35:44 AM »
well you's guys really put a lot of heart and soul into your product as long as it's for personal it's cool but when it becomes a trade it can be a problem depending on who you deal with but to go to these lengths, you must really love that molly.

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Re: Sassafras root bark
« Reply #14 on: February 13, 2010, 02:26:01 PM »
For those living on this side of the pond who are interested in raising Auritum I'd suggest getting a plant from Scotland (check RHS plantfinder) rather than sowing from seed. I found germination difficult though once through the seedling stage it doesn't need much attention. Its a tough little bugger though and continued to grow in an unheated house through the winter with outside temps down to -10c.  Re. extraction - I'm not there yet... lot, lot more growing to do...

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Re: Sassafras root bark
« Reply #15 on: February 13, 2010, 02:35:55 PM »
Honing your skills on this type shit does show love. The small trade that follows makes the connections that then help said "MacGyvers" to get real lab equipment and chinese oil brought right to them, if they want. Getting to that point by making damn near everything yourself keeps their exposure to a minimum. These kids should always remember the "middle man" nametag, even when you're not.

I do agree with jon. Life is way short. Work that they want you doing sucks. Drugs are awesome. Might as well profit.

But to say to most people to just go find good oil without connections is sending them to get ripped off if lucky, to hotel graybar if not.

"Look! Pure sassy on ebay! Comes complete with distilling kit and 1L rbfs!"

Back on off topic, There is a better design "cauldron", Vesp. It looks like a beer keg(and could be made from one) that has a basket that drops down in from the top. That way it has an insulating jacket of steam around the sides as well, only surface condensing is the top. But still, I think that style doesn't work well with these leaves. Big, flat, floppy. Tits in National Geographic. Anyway, I think the hot ticket would be to blender frozen leaves with water, toss in said device, heat and inject super heated steam. I never got to the super heated steam injection, but I'm sure it would rock.

Another advantage to both of these natural sources is that it helps one get a taste of the real. Once you know safrole it is easy to dip a finger, rub and sniff, but if you have only read, you have no clue what someone just sold you.

transient, even if he hasn't extracted yet can rub leaf and know what he is after.

Vesp

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Re: Sassafras root bark
« Reply #16 on: February 13, 2010, 08:22:50 PM »
Root bark, sure. Floppy leaves? I didn't think so. That is exactly what I was typing about. I have seen a number of the basket above water or superheated steam chamber essential oil distillers pics. You will see. Toss a bunch in that machine and you would have a big mass with vapor going around the sides. I still don't see it working right.

If you build a super critical co2 machine you could also make aerogel, I think ;)

Quote
Back on off topic, There is a better design "cauldron", Vesp. It looks like a beer keg(and could be made from one) that has a basket that drops down in from the top. That way it has an insulating jacket of steam around the sides as well, only surface condensing is the top. But still, I think that style doesn't work well with these leaves. Big, flat, floppy. Tits in National Geographic. Anyway, I think the hot ticket would be to blender frozen leaves with water, toss in said device, heat and inject super heated steam. I never got to the super heated steam injection, but I'm sure it would rock.


Oh I understand now! Perhaps just boiling the ground frozen leafs in water to make a soup, allowing to cool and then using ethyl acetate to extract the material with a few washes would be really effective. Distill the ethyl acetate, and then steam distill the, what I assume would be a black/green solidy goop?

This would be pretty labor intensive, but I think it would get most of the oils - and if you used the same water, and ethyl acetate each time -- you'd only lose it by what is left in the leafs, which would obviously be filtered and pressed after the boil.

I don't know... I haven't done many plant extractions of this sort before.


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Re: Sassafras root bark
« Reply #17 on: February 13, 2010, 10:04:30 PM »
Steam distilling takes heating, but I like how much volume you can process before getting to the chems. We are talking a lot of leaves here. Don't kid yourself. At least the steamed mess can be turned into the dirt and doesn't harm anything.

One tip for getting more "good stuff" is give the plants away to everyone you know and help them plant it. When I was extracting mescaline I gave everyone a san pedro cactus. ;) I had that shit planted everywhere. Never thought about doing that with the root beer plant until now.

Some wasps had asked about desert states, how about trying where the a/c drips? Kill 2 birds and get stoned!

Vesp

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Re: Sassafras root bark
« Reply #18 on: February 13, 2010, 10:19:11 PM »
Intresting idea... I was thinking it would probably grow well where the hostilis plants grow.. and then just water them more then ever, and keep a bunch in a lot of pots inside the house. Most things can live in the house... including my ~ 6 ft tobacco plant and a few others...
:D

I'm a fan of spreading plants and seeds around -- I often trade (on other sites) various seeds and plants for others.. or other items. I just haven't found anybody who has this plant, or would probably want to trade for it.
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Re: Sassafras root bark
« Reply #19 on: February 14, 2010, 04:29:27 PM »
It really isn't so hard to find this thing in the states. It is already there. Go to the Mexicans! They have it. Hoja Santa, say it with me "ohh-ha santa". Also just try big nurserys "root beer plant" or piper auritum, or my favorite, the nursery run by the crazy lady that has ever psychedelic plant you have ever thought of. The places that have jimson weed and morning glorys growing out front... heh.